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Article: Short-time photodissociation dynamics of 1-chloro-2-iodoethane from resonance Raman spectroscopy

TitleShort-time photodissociation dynamics of 1-chloro-2-iodoethane from resonance Raman spectroscopy
Authors
Keywords1-chloro-2-iodoethane
Iodoethane
Photodissociation
Raman
Resonance
Issue Date1999
PublisherHindawi Publishing Corp.
Citation
Laser Chemistry, 1999, v. 19 n. 1-4, p. 71-74 How to Cite?
AbstractWe have obtained A-band absorption resonance Raman spectra of 1-chloro-2-iodoethane in cyclohexane solution. We have done preliminary time-dependent wavepacket calculations to simulate the resonance Raman intensities and absorption spectrum in order to learn more about the short-time photodissociation dynamics. We compare our preliminary results for 1-chloro-2-iodoethane with previous resonance Raman results for iodoethane and find that there appears to be more motion along non-C-I stretch modes for 1-chloro-2-iodoethane than for iodoethane. This is consistent with results of TOF photofragment spectroscopy experiments which indicate much more internal excitation of the photoproducts from 1-chloro-2-iodoethane photodissociation than the photoproducts from iodoethane photodissociation. © 1999 OPA (Overseas Publishers Association) N.V. Published by licensed under the Harwood Academic Publishers imprint, part of The Gordon and Breach Publishing Group.
Persistent Identifierhttp://hdl.handle.net/10722/53323
ISSN
2004 Impact Factor: 0.4
2013 SCImago Journal Rankings: 0.131
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorZheng, Xen_HK
dc.contributor.authorPhillips, DLen_HK
dc.date.accessioned2009-04-03T07:12:24Z-
dc.date.available2009-04-03T07:12:24Z-
dc.date.issued1999en_HK
dc.identifier.citationLaser Chemistry, 1999, v. 19 n. 1-4, p. 71-74en_HK
dc.identifier.issn0278-6273en_HK
dc.identifier.urihttp://hdl.handle.net/10722/53323-
dc.description.abstractWe have obtained A-band absorption resonance Raman spectra of 1-chloro-2-iodoethane in cyclohexane solution. We have done preliminary time-dependent wavepacket calculations to simulate the resonance Raman intensities and absorption spectrum in order to learn more about the short-time photodissociation dynamics. We compare our preliminary results for 1-chloro-2-iodoethane with previous resonance Raman results for iodoethane and find that there appears to be more motion along non-C-I stretch modes for 1-chloro-2-iodoethane than for iodoethane. This is consistent with results of TOF photofragment spectroscopy experiments which indicate much more internal excitation of the photoproducts from 1-chloro-2-iodoethane photodissociation than the photoproducts from iodoethane photodissociation. © 1999 OPA (Overseas Publishers Association) N.V. Published by licensed under the Harwood Academic Publishers imprint, part of The Gordon and Breach Publishing Group.en_HK
dc.languageengen_HK
dc.publisherHindawi Publishing Corp.en_HK
dc.relation.ispartofLaser Chemistryen_HK
dc.rightsCreative Commons: Attribution 3.0 Hong Kong License-
dc.subject1-chloro-2-iodoethaneen_HK
dc.subjectIodoethaneen_HK
dc.subjectPhotodissociationen_HK
dc.subjectRamanen_HK
dc.subjectResonanceen_HK
dc.titleShort-time photodissociation dynamics of 1-chloro-2-iodoethane from resonance Raman spectroscopyen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0278-6273&volume=19&spage=71&epage=74&date=1999&atitle=Short-time+photodissociation+dynamics+of+1-chloro-2-iodoethane+from+resonance+raman+spectroscopyen_HK
dc.identifier.emailPhillips, DL:phillips@hku.hken_HK
dc.identifier.authorityPhillips, DL=rp00770en_HK
dc.description.naturepublished_or_final_versionen_HK
dc.identifier.doi10.1155/1999/53089en_HK
dc.identifier.scopuseid_2-s2.0-1342270728en_HK
dc.identifier.hkuros43760-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-1342270728&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume19en_HK
dc.identifier.issue1-4en_HK
dc.identifier.spage71en_HK
dc.identifier.epage74en_HK
dc.identifier.isiWOS:000081370000011-
dc.publisher.placeUnited Statesen_HK
dc.identifier.scopusauthoridZheng, X=7404090253en_HK
dc.identifier.scopusauthoridPhillips, DL=7404519365en_HK

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