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Article: Short-time photodissociation dynamics of 1-chloro-2-iodoethane from resonance Raman spectroscopy
Title | Short-time photodissociation dynamics of 1-chloro-2-iodoethane from resonance Raman spectroscopy |
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Authors | |
Keywords | 1-chloro-2-iodoethane Iodoethane Photodissociation Raman Resonance |
Issue Date | 1999 |
Publisher | Hindawi Publishing Corp. |
Citation | Laser Chemistry, 1999, v. 19 n. 1-4, p. 71-74 How to Cite? |
Abstract | We have obtained A-band absorption resonance Raman spectra of 1-chloro-2-iodoethane in cyclohexane solution. We have done preliminary time-dependent wavepacket calculations to simulate the resonance Raman intensities and absorption spectrum in order to learn more about the short-time photodissociation dynamics. We compare our preliminary results for 1-chloro-2-iodoethane with previous resonance Raman results for iodoethane and find that there appears to be more motion along non-C-I stretch modes for 1-chloro-2-iodoethane than for iodoethane. This is consistent with results of TOF photofragment spectroscopy experiments which indicate much more internal excitation of the photoproducts from 1-chloro-2-iodoethane photodissociation than the photoproducts from iodoethane photodissociation. © 1999 OPA (Overseas Publishers Association) N.V. Published by licensed under the Harwood Academic Publishers imprint, part of The Gordon and Breach Publishing Group. |
Persistent Identifier | http://hdl.handle.net/10722/53323 |
ISSN | |
ISI Accession Number ID | |
References |
DC Field | Value | Language |
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dc.contributor.author | Zheng, X | en_HK |
dc.contributor.author | Phillips, DL | en_HK |
dc.date.accessioned | 2009-04-03T07:12:24Z | - |
dc.date.available | 2009-04-03T07:12:24Z | - |
dc.date.issued | 1999 | en_HK |
dc.identifier.citation | Laser Chemistry, 1999, v. 19 n. 1-4, p. 71-74 | en_HK |
dc.identifier.issn | 0278-6273 | en_HK |
dc.identifier.uri | http://hdl.handle.net/10722/53323 | - |
dc.description.abstract | We have obtained A-band absorption resonance Raman spectra of 1-chloro-2-iodoethane in cyclohexane solution. We have done preliminary time-dependent wavepacket calculations to simulate the resonance Raman intensities and absorption spectrum in order to learn more about the short-time photodissociation dynamics. We compare our preliminary results for 1-chloro-2-iodoethane with previous resonance Raman results for iodoethane and find that there appears to be more motion along non-C-I stretch modes for 1-chloro-2-iodoethane than for iodoethane. This is consistent with results of TOF photofragment spectroscopy experiments which indicate much more internal excitation of the photoproducts from 1-chloro-2-iodoethane photodissociation than the photoproducts from iodoethane photodissociation. © 1999 OPA (Overseas Publishers Association) N.V. Published by licensed under the Harwood Academic Publishers imprint, part of The Gordon and Breach Publishing Group. | en_HK |
dc.language | eng | en_HK |
dc.publisher | Hindawi Publishing Corp. | en_HK |
dc.relation.ispartof | Laser Chemistry | en_HK |
dc.rights | This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License. | - |
dc.subject | 1-chloro-2-iodoethane | en_HK |
dc.subject | Iodoethane | en_HK |
dc.subject | Photodissociation | en_HK |
dc.subject | Raman | en_HK |
dc.subject | Resonance | en_HK |
dc.title | Short-time photodissociation dynamics of 1-chloro-2-iodoethane from resonance Raman spectroscopy | en_HK |
dc.type | Article | en_HK |
dc.identifier.openurl | http://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0278-6273&volume=19&spage=71&epage=74&date=1999&atitle=Short-time+photodissociation+dynamics+of+1-chloro-2-iodoethane+from+resonance+raman+spectroscopy | en_HK |
dc.identifier.email | Phillips, DL:phillips@hku.hk | en_HK |
dc.identifier.authority | Phillips, DL=rp00770 | en_HK |
dc.description.nature | published_or_final_version | en_HK |
dc.identifier.doi | 10.1155/1999/53089 | en_HK |
dc.identifier.scopus | eid_2-s2.0-1342270728 | en_HK |
dc.identifier.hkuros | 43760 | - |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-1342270728&selection=ref&src=s&origin=recordpage | en_HK |
dc.identifier.volume | 19 | en_HK |
dc.identifier.issue | 1-4 | en_HK |
dc.identifier.spage | 71 | en_HK |
dc.identifier.epage | 74 | en_HK |
dc.identifier.isi | WOS:000081370000011 | - |
dc.publisher.place | United States | en_HK |
dc.identifier.scopusauthorid | Zheng, X=7404090253 | en_HK |
dc.identifier.scopusauthorid | Phillips, DL=7404519365 | en_HK |
dc.identifier.issnl | 0278-6273 | - |