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Article: Time-resolved resonance Raman spectroscopy and density functional theory investigation of the CH2I-I isomer and CH2I2⋯I molecular complex products produced from ultraviolet photolysis of CH2I2 in the solution phase

TitleTime-resolved resonance Raman spectroscopy and density functional theory investigation of the CH2I-I isomer and CH2I2⋯I molecular complex products produced from ultraviolet photolysis of CH2I2 in the solution phase
Authors
KeywordsPhysics chemistry
Issue Date2002
PublisherAmerican Institute of Physics. The Journal's web site is located at http://jcp.aip.org/jcp/staff.jsp
Citation
Journal Of Chemical Physics, 2002, v. 117 n. 17, p. 7931-7941 How to Cite?
AbstractThe CH2I-I isomer and CH2I2···I molecular complex products produced from ultraviolet photolysis of CH2I2 in the solution phase was analyzed by using time-resolved resonance Raman spectroscopy. The structure and properties of the CH2I-I species and the CH2I2···I molecular complex and their reaction towards ethylene were compared. The results showed that the CH2I-I isomer reacts with ethylene to produce a cyclopropane product and I2 leaving group via a single step and low barrier to reaction.
Persistent Identifierhttp://hdl.handle.net/10722/42356
ISSN
2015 Impact Factor: 2.894
2015 SCImago Journal Rankings: 0.959
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorLi, YLen_HK
dc.contributor.authorWang, Den_HK
dc.contributor.authorPhillips, DLen_HK
dc.date.accessioned2007-01-29T08:47:40Z-
dc.date.available2007-01-29T08:47:40Z-
dc.date.issued2002en_HK
dc.identifier.citationJournal Of Chemical Physics, 2002, v. 117 n. 17, p. 7931-7941en_HK
dc.identifier.issn0021-9606en_HK
dc.identifier.urihttp://hdl.handle.net/10722/42356-
dc.description.abstractThe CH2I-I isomer and CH2I2···I molecular complex products produced from ultraviolet photolysis of CH2I2 in the solution phase was analyzed by using time-resolved resonance Raman spectroscopy. The structure and properties of the CH2I-I species and the CH2I2···I molecular complex and their reaction towards ethylene were compared. The results showed that the CH2I-I isomer reacts with ethylene to produce a cyclopropane product and I2 leaving group via a single step and low barrier to reaction.en_HK
dc.format.extent152754 bytes-
dc.format.extent30208 bytes-
dc.format.mimetypeapplication/pdf-
dc.format.mimetypeapplication/msword-
dc.languageengen_HK
dc.publisherAmerican Institute of Physics. The Journal's web site is located at http://jcp.aip.org/jcp/staff.jspen_HK
dc.relation.ispartofJournal of Chemical Physicsen_HK
dc.rightsCreative Commons: Attribution 3.0 Hong Kong License-
dc.subjectPhysics chemistryen_HK
dc.titleTime-resolved resonance Raman spectroscopy and density functional theory investigation of the CH2I-I isomer and CH2I2⋯I molecular complex products produced from ultraviolet photolysis of CH2I2 in the solution phaseen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0021-9606&volume=117&issue=17&spage=7931&epage=7941&date=2002&atitle=Time-resolved+resonance+Raman+spectroscopy+and+density+functional+theory+investigation+of+the+CH2I–+I+isomer+and+CH2I2...I+molecular+complex+products+produced+from+ultraviolet+photolysis+of+CH2I2+in+the+solution+phase:+Comparison+of+the+structure+and+chemical+reactivity+of+polyhalomethane+isomers+and+polyhalomethane–halogen+atom+molecular+complexesen_HK
dc.identifier.emailPhillips, DL:phillips@hku.hken_HK
dc.identifier.authorityPhillips, DL=rp00770en_HK
dc.description.naturepublished_or_final_versionen_HK
dc.identifier.doi10.1063/1.1511724en_HK
dc.identifier.scopuseid_2-s2.0-0036852571en_HK
dc.identifier.hkuros77157-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0036852571&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume117en_HK
dc.identifier.issue17en_HK
dc.identifier.spage7931en_HK
dc.identifier.epage7941en_HK
dc.identifier.isiWOS:000178625500014-
dc.publisher.placeUnited Statesen_HK
dc.identifier.scopusauthoridLi, YL=27168456500en_HK
dc.identifier.scopusauthoridWang, D=7407071795en_HK
dc.identifier.scopusauthoridPhillips, DL=7404519365en_HK

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