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Article: Time-resolved resonance Raman spectroscopy and density functional theory investigation of the CH2I-I isomer and CH2I2⋯I molecular complex products produced from ultraviolet photolysis of CH2I2 in the solution phase

TitleTime-resolved resonance Raman spectroscopy and density functional theory investigation of the CH2I-I isomer and CH2I2⋯I molecular complex products produced from ultraviolet photolysis of CH2I2 in the solution phase
Authors
Li, YLWang, DPhillips, DL
KeywordsPhysics chemistry
Issue Date2002
PublisherAmerican Institute of Physics. The Journal's web site is located at http://jcp.aip.org/jcp/staff.jsp
Citation
Journal of Chemical Physics, 2002, v. 117 n. 17, p. 7931-7941 How to Cite?
DOI: http://dx.doi.org/10.1063/1.1511724
AbstractThe CH2I-I isomer and CH2I2···I molecular complex products produced from ultraviolet photolysis of CH2I2 in the solution phase was analyzed by using time-resolved resonance Raman spectroscopy. The structure and properties of the CH2I-I species and the CH2I2···I molecular complex and their reaction towards ethylene were compared. The results showed that the CH2I-I isomer reacts with ethylene to produce a cyclopropane product and I2 leaving group via a single step and low barrier to reaction.
Persistent Identifierhttp://hdl.handle.net/10722/42356
ISSN
0021-9606
2023 Impact Factor: 3.1
2023 SCImago Journal Rankings: 1.101
ISI Accession Number ID
WOS:000178625500014
References
References in Scopus

 

DC FieldValueLanguage
dc.contributor.authorLi, YLen_HK
dc.contributor.authorWang, Den_HK
dc.contributor.authorPhillips, DLen_HK
dc.date.accessioned2007-01-29T08:47:40Z-
dc.date.available2007-01-29T08:47:40Z-
dc.date.issued2002en_HK
dc.identifier.citationJournal of Chemical Physics, 2002, v. 117 n. 17, p. 7931-7941-
dc.identifier.issn0021-9606en_HK
dc.identifier.urihttp://hdl.handle.net/10722/42356-
dc.description.abstractThe CH2I-I isomer and CH2I2···I molecular complex products produced from ultraviolet photolysis of CH2I2 in the solution phase was analyzed by using time-resolved resonance Raman spectroscopy. The structure and properties of the CH2I-I species and the CH2I2···I molecular complex and their reaction towards ethylene were compared. The results showed that the CH2I-I isomer reacts with ethylene to produce a cyclopropane product and I2 leaving group via a single step and low barrier to reaction.en_HK
dc.format.extent152754 bytes-
dc.format.extent30208 bytes-
dc.format.mimetypeapplication/pdf-
dc.format.mimetypeapplication/msword-
dc.languageengen_HK
dc.publisherAmerican Institute of Physics. The Journal's web site is located at http://jcp.aip.org/jcp/staff.jspen_HK
dc.relation.ispartofJournal of Chemical Physicsen_HK
dc.rightsCopyright 2002 American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics. The following article appeared in Journal of Chemical Physics, 2002, v. 117 n. 17, p. 7931-7941 and may be found at https://doi.org/10.1063/1.1511724-
dc.subjectPhysics chemistryen_HK
dc.titleTime-resolved resonance Raman spectroscopy and density functional theory investigation of the CH2I-I isomer and CH2I2⋯I molecular complex products produced from ultraviolet photolysis of CH2I2 in the solution phaseen_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0021-9606&volume=117&issue=17&spage=7931&epage=7941&date=2002&atitle=Time-resolved+resonance+Raman+spectroscopy+and+density+functional+theory+investigation+of+the+CH2I–+I+isomer+and+CH2I2...I+molecular+complex+products+produced+from+ultraviolet+photolysis+of+CH2I2+in+the+solution+phase:+Comparison+of+the+structure+and+chemical+reactivity+of+polyhalomethane+isomers+and+polyhalomethane–halogen+atom+molecular+complexesen_HK
dc.identifier.emailPhillips, DL:phillips@hku.hken_HK
dc.identifier.authorityPhillips, DL=rp00770en_HK
dc.description.naturepublished_or_final_versionen_HK
dc.identifier.doi10.1063/1.1511724en_HK
dc.identifier.scopuseid_2-s2.0-0036852571en_HK
dc.identifier.hkuros77157-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0036852571&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume117en_HK
dc.identifier.issue17en_HK
dc.identifier.spage7931en_HK
dc.identifier.epage7941en_HK
dc.identifier.isiWOS:000178625500014-
dc.publisher.placeUnited Statesen_HK
dc.identifier.scopusauthoridLi, YL=27168456500en_HK
dc.identifier.scopusauthoridWang, D=7407071795en_HK
dc.identifier.scopusauthoridPhillips, DL=7404519365en_HK
dc.identifier.issnl0021-9606-

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