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Article: Transient resonance Raman spectroscopy and density functional theory investigation of iso-CHBr 2Cl and iso-CCl 3Br photoproducts produced following ultraviolet excitation of CHBr 2Cl and CCl 3Br

TitleTransient resonance Raman spectroscopy and density functional theory investigation of iso-CHBr 2Cl and iso-CCl 3Br photoproducts produced following ultraviolet excitation of CHBr 2Cl and CCl 3Br
Authors
KeywordsPhysics chemistry
Issue Date2001
PublisherAmerican Institute of Physics. The Journal's web site is located at http://jcp.aip.org/jcp/staff.jsp
Citation
Journal Of Chemical Physics, 2001, v. 114 n. 19, p. 8347-8356 How to Cite?
AbstractTwo polyhalomethanes that contain bromine and chlorine atoms (CHBr 2Cl and CCl 2Br) were studied. Transient resonance Raman spectra were obtained for the photoproducts produced after ultraviolet excitation of CHBr 2Cl and CCl 3Br in room temperature solutions and density functional theory calculations for species proposed to be products of the photodissociation reactions in the solution phase. It was found that the iso-CHBrCl-Br and iso-CHClBr-Br species are formed following ultraviolet excitation of CHBr 2Cl and the iso-CCl 2Cl-Br species formed following ultraviolet excitation of CCl 3Br in the solution phase.
Persistent Identifierhttp://hdl.handle.net/10722/42353
ISSN
2015 Impact Factor: 2.894
2015 SCImago Journal Rankings: 0.959
ISI Accession Number ID
References

 

DC FieldValueLanguage
dc.contributor.authorZheng, Xen_HK
dc.contributor.authorLee, CWen_HK
dc.contributor.authorLi, YLen_HK
dc.contributor.authorFang, WHen_HK
dc.contributor.authorPhillips, DLen_HK
dc.date.accessioned2007-01-29T08:47:36Z-
dc.date.available2007-01-29T08:47:36Z-
dc.date.issued2001en_HK
dc.identifier.citationJournal Of Chemical Physics, 2001, v. 114 n. 19, p. 8347-8356en_HK
dc.identifier.issn0021-9606en_HK
dc.identifier.urihttp://hdl.handle.net/10722/42353-
dc.description.abstractTwo polyhalomethanes that contain bromine and chlorine atoms (CHBr 2Cl and CCl 2Br) were studied. Transient resonance Raman spectra were obtained for the photoproducts produced after ultraviolet excitation of CHBr 2Cl and CCl 3Br in room temperature solutions and density functional theory calculations for species proposed to be products of the photodissociation reactions in the solution phase. It was found that the iso-CHBrCl-Br and iso-CHClBr-Br species are formed following ultraviolet excitation of CHBr 2Cl and the iso-CCl 2Cl-Br species formed following ultraviolet excitation of CCl 3Br in the solution phase.en_HK
dc.format.extent126442 bytes-
dc.format.extent30208 bytes-
dc.format.mimetypeapplication/pdf-
dc.format.mimetypeapplication/msword-
dc.languageengen_HK
dc.publisherAmerican Institute of Physics. The Journal's web site is located at http://jcp.aip.org/jcp/staff.jspen_HK
dc.relation.ispartofJournal of Chemical Physicsen_HK
dc.rightsCreative Commons: Attribution 3.0 Hong Kong License-
dc.subjectPhysics chemistryen_HK
dc.titleTransient resonance Raman spectroscopy and density functional theory investigation of iso-CHBr 2Cl and iso-CCl 3Br photoproducts produced following ultraviolet excitation of CHBr 2Cl and CCl 3Bren_HK
dc.typeArticleen_HK
dc.identifier.openurlhttp://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0021-9606&volume=114&issue=19&spage=8347&epage=8356&date=2001&atitle=Transient+resonance+Raman+spectroscopy+and+density+functional+theory+investigation+of+iso-CHBr2Cl+and+iso-CCl3Br+photoproducts+produced+following+ultraviolet+excitation+of+CHBr2Cl+and+CCl3Bren_HK
dc.identifier.emailPhillips, DL:phillips@hku.hken_HK
dc.identifier.authorityPhillips, DL=rp00770en_HK
dc.description.naturepublished_or_final_versionen_HK
dc.identifier.doi10.1063/1.1367391en_HK
dc.identifier.scopuseid_2-s2.0-0035872822en_HK
dc.identifier.hkuros62458-
dc.relation.referenceshttp://www.scopus.com/mlt/select.url?eid=2-s2.0-0035872822&selection=ref&src=s&origin=recordpageen_HK
dc.identifier.volume114en_HK
dc.identifier.issue19en_HK
dc.identifier.spage8347en_HK
dc.identifier.epage8356en_HK
dc.identifier.isiWOS:000168440400016-
dc.publisher.placeUnited Statesen_HK
dc.identifier.scopusauthoridZheng, X=7404090253en_HK
dc.identifier.scopusauthoridLee, CW=7410160954en_HK
dc.identifier.scopusauthoridLi, YL=27168456500en_HK
dc.identifier.scopusauthoridFang, WH=7202236871en_HK
dc.identifier.scopusauthoridPhillips, DL=7404519365en_HK

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