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Article: Transient resonance Raman spectroscopy and density functional theory investigation of iso-CHBr 2Cl and iso-CCl 3Br photoproducts produced following ultraviolet excitation of CHBr 2Cl and CCl 3Br
Title | Transient resonance Raman spectroscopy and density functional theory investigation of iso-CHBr 2Cl and iso-CCl 3Br photoproducts produced following ultraviolet excitation of CHBr 2Cl and CCl 3Br |
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Authors | |
Keywords | Physics chemistry |
Issue Date | 2001 |
Publisher | American Institute of Physics. The Journal's web site is located at http://jcp.aip.org/jcp/staff.jsp |
Citation | Journal of Chemical Physics, 2001, v. 114 n. 19, p. 8347-8356 How to Cite? |
Abstract | Two polyhalomethanes that contain bromine and chlorine atoms (CHBr 2Cl and CCl 2Br) were studied. Transient resonance Raman spectra were obtained for the photoproducts produced after ultraviolet excitation of CHBr 2Cl and CCl 3Br in room temperature solutions and density functional theory calculations for species proposed to be products of the photodissociation reactions in the solution phase. It was found that the iso-CHBrCl-Br and iso-CHClBr-Br species are formed following ultraviolet excitation of CHBr 2Cl and the iso-CCl 2Cl-Br species formed following ultraviolet excitation of CCl 3Br in the solution phase. |
Persistent Identifier | http://hdl.handle.net/10722/42353 |
ISSN | 2023 Impact Factor: 3.1 2023 SCImago Journal Rankings: 1.101 |
ISI Accession Number ID | |
References |
DC Field | Value | Language |
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dc.contributor.author | Zheng, X | en_HK |
dc.contributor.author | Lee, CW | en_HK |
dc.contributor.author | Li, YL | en_HK |
dc.contributor.author | Fang, WH | en_HK |
dc.contributor.author | Phillips, DL | en_HK |
dc.date.accessioned | 2007-01-29T08:47:36Z | - |
dc.date.available | 2007-01-29T08:47:36Z | - |
dc.date.issued | 2001 | en_HK |
dc.identifier.citation | Journal of Chemical Physics, 2001, v. 114 n. 19, p. 8347-8356 | - |
dc.identifier.issn | 0021-9606 | en_HK |
dc.identifier.uri | http://hdl.handle.net/10722/42353 | - |
dc.description.abstract | Two polyhalomethanes that contain bromine and chlorine atoms (CHBr 2Cl and CCl 2Br) were studied. Transient resonance Raman spectra were obtained for the photoproducts produced after ultraviolet excitation of CHBr 2Cl and CCl 3Br in room temperature solutions and density functional theory calculations for species proposed to be products of the photodissociation reactions in the solution phase. It was found that the iso-CHBrCl-Br and iso-CHClBr-Br species are formed following ultraviolet excitation of CHBr 2Cl and the iso-CCl 2Cl-Br species formed following ultraviolet excitation of CCl 3Br in the solution phase. | en_HK |
dc.format.extent | 126442 bytes | - |
dc.format.extent | 30208 bytes | - |
dc.format.mimetype | application/pdf | - |
dc.format.mimetype | application/msword | - |
dc.language | eng | en_HK |
dc.publisher | American Institute of Physics. The Journal's web site is located at http://jcp.aip.org/jcp/staff.jsp | en_HK |
dc.relation.ispartof | Journal of Chemical Physics | en_HK |
dc.rights | Copyright 2001 American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics. The following article appeared in Journal of Chemical Physics, 2001, v. 114 n. 19, p. 8347-8356 and may be found at https://doi.org/10.1063/1.1367391 | - |
dc.subject | Physics chemistry | en_HK |
dc.title | Transient resonance Raman spectroscopy and density functional theory investigation of iso-CHBr 2Cl and iso-CCl 3Br photoproducts produced following ultraviolet excitation of CHBr 2Cl and CCl 3Br | en_HK |
dc.type | Article | en_HK |
dc.identifier.openurl | http://library.hku.hk:4550/resserv?sid=HKU:IR&issn=0021-9606&volume=114&issue=19&spage=8347&epage=8356&date=2001&atitle=Transient+resonance+Raman+spectroscopy+and+density+functional+theory+investigation+of+iso-CHBr2Cl+and+iso-CCl3Br+photoproducts+produced+following+ultraviolet+excitation+of+CHBr2Cl+and+CCl3Br | en_HK |
dc.identifier.email | Phillips, DL:phillips@hku.hk | en_HK |
dc.identifier.authority | Phillips, DL=rp00770 | en_HK |
dc.description.nature | published_or_final_version | en_HK |
dc.identifier.doi | 10.1063/1.1367391 | en_HK |
dc.identifier.scopus | eid_2-s2.0-0035872822 | en_HK |
dc.identifier.hkuros | 62458 | - |
dc.relation.references | http://www.scopus.com/mlt/select.url?eid=2-s2.0-0035872822&selection=ref&src=s&origin=recordpage | en_HK |
dc.identifier.volume | 114 | en_HK |
dc.identifier.issue | 19 | en_HK |
dc.identifier.spage | 8347 | en_HK |
dc.identifier.epage | 8356 | en_HK |
dc.identifier.isi | WOS:000168440400016 | - |
dc.publisher.place | United States | en_HK |
dc.identifier.scopusauthorid | Zheng, X=7404090253 | en_HK |
dc.identifier.scopusauthorid | Lee, CW=7410160954 | en_HK |
dc.identifier.scopusauthorid | Li, YL=27168456500 | en_HK |
dc.identifier.scopusauthorid | Fang, WH=7202236871 | en_HK |
dc.identifier.scopusauthorid | Phillips, DL=7404519365 | en_HK |
dc.identifier.issnl | 0021-9606 | - |