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Article: Arenium acid catalyzed deuteration of aromatic hydrocarbons

TitleArenium acid catalyzed deuteration of aromatic hydrocarbons
Authors
Duttwyler, SimonButterfield, Anna M.Siegel, Jay S.
Issue Date2013
Citation
Journal of Organic Chemistry, 2013, v. 78, n. 5, p. 2134-2138 How to Cite?
DOI: http://dx.doi.org/10.1021/jo302201a
AbstractThe arenium acid [mesitylene-H]+ has been shown to be an extraordinarily active H/D exchange catalyst for the perdeuteration of polycyclic aromatic hydrocarbons. The reactions take place under ambient conditions in C6D6 as an inexpensive deuterium source. High isolated yields and excellent degrees of deuterium incorporation were achieved using the substrates p-terphenyl, fluoranthene, pyrene, triphenylene, and corannulene. © 2012 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/341135
ISSN
0022-3263
2021 Impact Factor: 4.198
2020 SCImago Journal Rankings: 1.200
ISI Accession Number ID
WOS:000315707500053

 

DC FieldValueLanguage
dc.contributor.authorDuttwyler, Simon-
dc.contributor.authorButterfield, Anna M.-
dc.contributor.authorSiegel, Jay S.-
dc.date.accessioned2024-03-13T08:40:26Z-
dc.date.available2024-03-13T08:40:26Z-
dc.date.issued2013-
dc.identifier.citationJournal of Organic Chemistry, 2013, v. 78, n. 5, p. 2134-2138-
dc.identifier.issn0022-3263-
dc.identifier.urihttp://hdl.handle.net/10722/341135-
dc.description.abstractThe arenium acid [mesitylene-H]+ has been shown to be an extraordinarily active H/D exchange catalyst for the perdeuteration of polycyclic aromatic hydrocarbons. The reactions take place under ambient conditions in C6D6 as an inexpensive deuterium source. High isolated yields and excellent degrees of deuterium incorporation were achieved using the substrates p-terphenyl, fluoranthene, pyrene, triphenylene, and corannulene. © 2012 American Chemical Society.-
dc.languageeng-
dc.relation.ispartofJournal of Organic Chemistry-
dc.titleArenium acid catalyzed deuteration of aromatic hydrocarbons-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/jo302201a-
dc.identifier.pmid23163918-
dc.identifier.scopuseid_2-s2.0-84874584201-
dc.identifier.volume78-
dc.identifier.issue5-
dc.identifier.spage2134-
dc.identifier.epage2138-
dc.identifier.eissn1520-6904-
dc.identifier.isiWOS:000315707500053-

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