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Article: Synthesis and X-ray structural analysis of platinum and ethynyl-platinum corannulenes: Supramolecular tectons

TitleSynthesis and X-ray structural analysis of platinum and ethynyl-platinum corannulenes: Supramolecular tectons
Authors
Maag, RomanNorthrop, Brian H.Butterfield, AnnaLinden, AnthonyZerbe, OliverLee, Young MinChi, Ki WhanStang, Peter J.Siegel, Jay S.
Issue Date2009
Citation
Organic and Biomolecular Chemistry, 2009, v. 7, n. 23, p. 4881-4885 How to Cite?
DOI: http://dx.doi.org/10.1039/b916020e
AbstractThe synthesis and characterization of two direct platinum (1 and 6a/b) and three ethynyl-platinum corannulene derivatives (2, 8 and 9), bearing 2, 4, or 5 square planar platinum centers, are presented. The structure of the bowl bearing substituents remains comparable to corannulene and the dynamic behavior of the bowl inversion as assessed by VT NMR supports a persistent bowl structure in solution. These platinum-corannulenes are well-structured tectons for the future assembly of coordination Platonic polyhedra. © The Royal Society of Chemistry 2009.
Persistent Identifierhttp://hdl.handle.net/10722/341113
ISSN
1477-0520
2021 Impact Factor: 3.890
2020 SCImago Journal Rankings: 0.923

 

DC FieldValueLanguage
dc.contributor.authorMaag, Roman-
dc.contributor.authorNorthrop, Brian H.-
dc.contributor.authorButterfield, Anna-
dc.contributor.authorLinden, Anthony-
dc.contributor.authorZerbe, Oliver-
dc.contributor.authorLee, Young Min-
dc.contributor.authorChi, Ki Whan-
dc.contributor.authorStang, Peter J.-
dc.contributor.authorSiegel, Jay S.-
dc.date.accessioned2024-03-13T08:40:15Z-
dc.date.available2024-03-13T08:40:15Z-
dc.date.issued2009-
dc.identifier.citationOrganic and Biomolecular Chemistry, 2009, v. 7, n. 23, p. 4881-4885-
dc.identifier.issn1477-0520-
dc.identifier.urihttp://hdl.handle.net/10722/341113-
dc.description.abstractThe synthesis and characterization of two direct platinum (1 and 6a/b) and three ethynyl-platinum corannulene derivatives (2, 8 and 9), bearing 2, 4, or 5 square planar platinum centers, are presented. The structure of the bowl bearing substituents remains comparable to corannulene and the dynamic behavior of the bowl inversion as assessed by VT NMR supports a persistent bowl structure in solution. These platinum-corannulenes are well-structured tectons for the future assembly of coordination Platonic polyhedra. © The Royal Society of Chemistry 2009.-
dc.languageeng-
dc.relation.ispartofOrganic and Biomolecular Chemistry-
dc.titleSynthesis and X-ray structural analysis of platinum and ethynyl-platinum corannulenes: Supramolecular tectons-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1039/b916020e-
dc.identifier.pmid19907778-
dc.identifier.scopuseid_2-s2.0-72449133949-
dc.identifier.volume7-
dc.identifier.issue23-
dc.identifier.spage4881-
dc.identifier.epage4885-

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