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Article: Dilithiation of Two Diphenyl Ethers Each Containing Two NHCH2CH2Y (Y = OMe, NMe2) Side Arms in ortho Positions: Assembly of “Adamantanoid” Li4O2N4 Cores

TitleDilithiation of Two Diphenyl Ethers Each Containing Two NHCH<inf>2</inf>CH<inf>2</inf>Y (Y = OMe, NMe<inf>2</inf>) Side Arms in ortho Positions: Assembly of “Adamantanoid” Li<inf>4</inf>O<inf>2</inf>N<inf>4</inf> Cores
Authors
Issue Date1993
Citation
Angewandte Chemie International Edition in English, 1993, v. 32, n. 8, p. 1182-1184 How to Cite?
AbstractNo N2Li2 units are formed on dilithiation of the RNH‐substituted ethers 1 and 2. Instead, the dimerization of two monomers leads to adamantanoid structures with Li4O2N4 frameworks and CH2CH2OMe and CH2CH2NMe2 side arms that are crucial for dimer formation. The adamantanoid structure of the Li2 compound prepared from 1 also persists in solution. (Figure Presented.) Copyright © 1993 by VCH Verlagsgesellschaft mbH, Germany
Persistent Identifierhttp://hdl.handle.net/10722/333599
ISSN
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorCragg‐Hine, Ian-
dc.contributor.authorDavidson, Matthew G.-
dc.contributor.authorKocian, Oldrich-
dc.contributor.authorMair, Francis S.-
dc.contributor.authorPohl, Ehmke-
dc.contributor.authorRaithby, Paul R.-
dc.contributor.authorSnaith, Ronald-
dc.contributor.authorSpencer, Neil-
dc.contributor.authorStoddart, J. Fraser-
dc.date.accessioned2023-10-06T05:20:55Z-
dc.date.available2023-10-06T05:20:55Z-
dc.date.issued1993-
dc.identifier.citationAngewandte Chemie International Edition in English, 1993, v. 32, n. 8, p. 1182-1184-
dc.identifier.issn0570-0833-
dc.identifier.urihttp://hdl.handle.net/10722/333599-
dc.description.abstractNo N2Li2 units are formed on dilithiation of the RNH‐substituted ethers 1 and 2. Instead, the dimerization of two monomers leads to adamantanoid structures with Li4O2N4 frameworks and CH2CH2OMe and CH2CH2NMe2 side arms that are crucial for dimer formation. The adamantanoid structure of the Li2 compound prepared from 1 also persists in solution. (Figure Presented.) Copyright © 1993 by VCH Verlagsgesellschaft mbH, Germany-
dc.languageeng-
dc.relation.ispartofAngewandte Chemie International Edition in English-
dc.titleDilithiation of Two Diphenyl Ethers Each Containing Two NHCH<inf>2</inf>CH<inf>2</inf>Y (Y = OMe, NMe<inf>2</inf>) Side Arms in ortho Positions: Assembly of “Adamantanoid” Li<inf>4</inf>O<inf>2</inf>N<inf>4</inf> Cores-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1002/anie.199311821-
dc.identifier.scopuseid_2-s2.0-33748216134-
dc.identifier.volume32-
dc.identifier.issue8-
dc.identifier.spage1182-
dc.identifier.epage1184-
dc.identifier.eissn1521-3773-
dc.identifier.isiWOS:A1993LU33800026-

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