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Article: Postsynthetic Incorporation of a Singlet Oxygen Photosensitizer in a Metal–Organic Framework for Fast and Selective Oxidative Detoxification of Sulfur Mustard

TitlePostsynthetic Incorporation of a Singlet Oxygen Photosensitizer in a Metal–Organic Framework for Fast and Selective Oxidative Detoxification of Sulfur Mustard
Authors
Howarth, Ashlee J.Buru, Cassandra T.Liu, YangyangPloskonka, Ann M.Hartlieb, Karel J.McEntee, MonicaMahle, John J.Buchanan, James H.Durke, Erin M.Al-Juaid, Salih S.Stoddart, J. FraserDeCoste, Jared B.Hupp, Joseph T.Farha, Omar K.
Keywordsfullerene
metal–organic frameworks
pyrene
singlet oxygen
sulfur mustard
Issue Date2017
Citation
Chemistry - A European Journal, 2017, v. 23, n. 1, p. 214-218 How to Cite?
DOI: http://dx.doi.org/10.1002/chem.201604972
AbstractA fullerene-based photosensitizer is incorporated postsynthetically into a Zr6-based MOF, NU-1000, for enhanced singlet oxygen production. The structural organic linkers in the MOF platform also act as photosensitizers which contribute to the overall generation of singlet oxygen from the material under UV irradiation. The singlet oxygen generated by the MOF/fullerene material is shown to oxidize sulfur mustard selectively to the less toxic bis(2-chloroethyl)sulfoxide with a half-life of only 11 min.
Persistent Identifierhttp://hdl.handle.net/10722/333251
ISSN
0947-6539
2021 Impact Factor: 5.020
2020 SCImago Journal Rankings: 1.687
ISI Accession Number ID
WOS:000393599700032

 

DC FieldValueLanguage
dc.contributor.authorHowarth, Ashlee J.-
dc.contributor.authorBuru, Cassandra T.-
dc.contributor.authorLiu, Yangyang-
dc.contributor.authorPloskonka, Ann M.-
dc.contributor.authorHartlieb, Karel J.-
dc.contributor.authorMcEntee, Monica-
dc.contributor.authorMahle, John J.-
dc.contributor.authorBuchanan, James H.-
dc.contributor.authorDurke, Erin M.-
dc.contributor.authorAl-Juaid, Salih S.-
dc.contributor.authorStoddart, J. Fraser-
dc.contributor.authorDeCoste, Jared B.-
dc.contributor.authorHupp, Joseph T.-
dc.contributor.authorFarha, Omar K.-
dc.date.accessioned2023-10-06T05:17:53Z-
dc.date.available2023-10-06T05:17:53Z-
dc.date.issued2017-
dc.identifier.citationChemistry - A European Journal, 2017, v. 23, n. 1, p. 214-218-
dc.identifier.issn0947-6539-
dc.identifier.urihttp://hdl.handle.net/10722/333251-
dc.description.abstractA fullerene-based photosensitizer is incorporated postsynthetically into a Zr6-based MOF, NU-1000, for enhanced singlet oxygen production. The structural organic linkers in the MOF platform also act as photosensitizers which contribute to the overall generation of singlet oxygen from the material under UV irradiation. The singlet oxygen generated by the MOF/fullerene material is shown to oxidize sulfur mustard selectively to the less toxic bis(2-chloroethyl)sulfoxide with a half-life of only 11 min.-
dc.languageeng-
dc.relation.ispartofChemistry - A European Journal-
dc.subjectfullerene-
dc.subjectmetal–organic frameworks-
dc.subjectpyrene-
dc.subjectsinglet oxygen-
dc.subjectsulfur mustard-
dc.titlePostsynthetic Incorporation of a Singlet Oxygen Photosensitizer in a Metal–Organic Framework for Fast and Selective Oxidative Detoxification of Sulfur Mustard-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1002/chem.201604972-
dc.identifier.pmid27780293-
dc.identifier.scopuseid_2-s2.0-85006063449-
dc.identifier.volume23-
dc.identifier.issue1-
dc.identifier.spage214-
dc.identifier.epage218-
dc.identifier.eissn1521-3765-
dc.identifier.isiWOS:000393599700032-

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