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Article: Complexing properties of a bisdianhydro-D-mannitolo-30-crown-10 derivative in the solution and solid states; X-ray crystal structure

TitleComplexing properties of a bisdianhydro-D-mannitolo-30-crown-10 derivative in the solution and solid states; X-ray crystal structure
Authors
Metcalfe, Janet C.Stoddart, J. FraserJones, GeraintCrawshaw, Thomas H.Gavuzzo, EnricoWilliams, David J.
Issue Date1981
Citation
Journal of the Chemical Society, Chemical Communications, 1981, n. 9, p. 432-434 How to Cite?
DOI: http://dx.doi.org/10.1039/C39810000432
AbstractX-Ray crystallography has revealed that the chiral 30-crown-10 derivative DD-(2) adopts a basketlike conformation when it forms a 1:1:1 complex with (S)-[PhCHMeNH3]+ ClO4- and H 2O in the solid state; 1H n.m.r. spectroscopy suggests that 1:1:1 complexes of this type between (i) DD-(2), R1NH 3+ cations, and H2O, and (ii) DD-(2), R 1NH3+ cations, and R2NH2 are also stable in solution.
Persistent Identifierhttp://hdl.handle.net/10722/332795
ISSN
0022-4936
ISI Accession Number ID
WOS:A1981LP46800028

 

DC FieldValueLanguage
dc.contributor.authorMetcalfe, Janet C.-
dc.contributor.authorStoddart, J. Fraser-
dc.contributor.authorJones, Geraint-
dc.contributor.authorCrawshaw, Thomas H.-
dc.contributor.authorGavuzzo, Enrico-
dc.contributor.authorWilliams, David J.-
dc.date.accessioned2023-10-06T05:14:20Z-
dc.date.available2023-10-06T05:14:20Z-
dc.date.issued1981-
dc.identifier.citationJournal of the Chemical Society, Chemical Communications, 1981, n. 9, p. 432-434-
dc.identifier.issn0022-4936-
dc.identifier.urihttp://hdl.handle.net/10722/332795-
dc.description.abstractX-Ray crystallography has revealed that the chiral 30-crown-10 derivative DD-(2) adopts a basketlike conformation when it forms a 1:1:1 complex with (S)-[PhCHMeNH<inf>3</inf>]<sup>+</sup> ClO<inf>4</inf><sup>-</sup> and H <inf>2</inf>O in the solid state; <sup>1</sup>H n.m.r. spectroscopy suggests that 1:1:1 complexes of this type between (i) DD-(2), R<sup>1</sup>NH <inf>3</inf><sup>+</sup> cations, and H<inf>2</inf>O, and (ii) DD-(2), R <sup>1</sup>NH<inf>3</inf><sup>+</sup> cations, and R<sup>2</sup>NH<inf>2</inf> are also stable in solution.-
dc.languageeng-
dc.relation.ispartofJournal of the Chemical Society, Chemical Communications-
dc.titleComplexing properties of a bisdianhydro-D-mannitolo-30-crown-10 derivative in the solution and solid states; X-ray crystal structure-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1039/C39810000432-
dc.identifier.scopuseid_2-s2.0-37049099981-
dc.identifier.issue9-
dc.identifier.spage432-
dc.identifier.epage434-
dc.identifier.isiWOS:A1981LP46800028-

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