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- Publisher Website: 10.1039/C39930001355
- Scopus: eid_2-s2.0-37049090539
- WOS: WOS:A1993LW75000024
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Article: Monometallation of a di(aminoaryl) ether induces a Smiles rearrangement leading to a sodium aryloxide complex: The synthesis and crystal structure of [(MeOCH2 CH2 )(C6 H4 NHCH 2 CH2 OMe)NC6 H4 O·Na] 2
| Title | Monometallation of a di(aminoaryl) ether induces a Smiles rearrangement leading to a sodium aryloxide complex: The synthesis and crystal structure of [(MeOCH<inf>2</inf>CH<inf>2</inf>)(C<inf>6</inf>H<inf>4</inf>NHCH <inf>2</inf>CH<inf>2</inf>OMe)NC<inf>6</inf>H<inf>4</inf>O·Na] <inf>2</inf> |
|---|---|
| Authors | |
| Issue Date | 1993 |
| Citation | Journal of the Chemical Society, Chemical Communications, 1993, n. 17, p. 1355-1357 How to Cite? |
| Abstract | The title compound was synthesised by 1: 1 reaction of sodium hydride with a di(aminoaryl) ether ligand in toluene-hexamethylphosphoramide (HMPA) solution; X-ray crystallography revealed that an in situ Smiles rearrangement of the ligand had taken place to give a dimeric aryloxide sodium complex, which is in stark contrast to previous results obtained by 2: 1 reaction of BunLi with the ligand in the absence of HMPA. |
| Persistent Identifier | http://hdl.handle.net/10722/332777 |
| ISSN | |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Cragg-Hine, Ian | - |
| dc.contributor.author | Davidson, Matthew G. | - |
| dc.contributor.author | Kocian, Oldrich | - |
| dc.contributor.author | Kottke, Thomas | - |
| dc.contributor.author | Mair, Francis S. | - |
| dc.contributor.author | Snaith, Ronald | - |
| dc.contributor.author | Stoddart, J. Fraser | - |
| dc.date.accessioned | 2023-10-06T05:14:12Z | - |
| dc.date.available | 2023-10-06T05:14:12Z | - |
| dc.date.issued | 1993 | - |
| dc.identifier.citation | Journal of the Chemical Society, Chemical Communications, 1993, n. 17, p. 1355-1357 | - |
| dc.identifier.issn | 0022-4936 | - |
| dc.identifier.uri | http://hdl.handle.net/10722/332777 | - |
| dc.description.abstract | The title compound was synthesised by 1: 1 reaction of sodium hydride with a di(aminoaryl) ether ligand in toluene-hexamethylphosphoramide (HMPA) solution; X-ray crystallography revealed that an in situ Smiles rearrangement of the ligand had taken place to give a dimeric aryloxide sodium complex, which is in stark contrast to previous results obtained by 2: 1 reaction of BunLi with the ligand in the absence of HMPA. | - |
| dc.language | eng | - |
| dc.relation.ispartof | Journal of the Chemical Society, Chemical Communications | - |
| dc.title | Monometallation of a di(aminoaryl) ether induces a Smiles rearrangement leading to a sodium aryloxide complex: The synthesis and crystal structure of [(MeOCH<inf>2</inf>CH<inf>2</inf>)(C<inf>6</inf>H<inf>4</inf>NHCH <inf>2</inf>CH<inf>2</inf>OMe)NC<inf>6</inf>H<inf>4</inf>O·Na] <inf>2</inf> | - |
| dc.type | Article | - |
| dc.description.nature | link_to_subscribed_fulltext | - |
| dc.identifier.doi | 10.1039/C39930001355 | - |
| dc.identifier.scopus | eid_2-s2.0-37049090539 | - |
| dc.identifier.issue | 17 | - |
| dc.identifier.spage | 1355 | - |
| dc.identifier.epage | 1357 | - |
| dc.identifier.isi | WOS:A1993LW75000024 | - |