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- Publisher Website: 10.1021/jo050969b
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Article: Nanoscale borromeates
Title | Nanoscale borromeates |
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Authors | |
Issue Date | 2005 |
Citation | Journal of Organic Chemistry, 2005, v. 70, n. 20, p. 7956-7962 How to Cite? |
Abstract | In addition to a parent zinc(II) Borromean ring (BR) complex, the preparation and characterization of two hexasubstituted BR complexes with either 4-acetoxymethylphenyl or 4-methylthiophenyl substituents associated in turn with all six pyridyl rings has been achieved convergently in good yields by appealing to the dynamic features of the reactions between primary amino groups in a preformed acyclic ligand and 2,6-diformylpyridine. Two molecules of the acyclic ligands react with two molecules of 2,6-diformylpyridine to form a cyclic [2 + 2] tetraimine in the presence of Zn(II) ions as templates in 2-propanol at 70 °C. The successful preparation of the two derivatives by convergent template-directed syntheses opens up opportunities to self-assemble, under equilibrium control, numerous nanoscale metallo-organic particles with potentially useful properties. © 2005 American Chemical Society. |
Persistent Identifier | http://hdl.handle.net/10722/332626 |
ISSN | 2021 Impact Factor: 4.198 2020 SCImago Journal Rankings: 1.200 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Chichak, Kelly S. | - |
dc.contributor.author | Peters, Andrea J. | - |
dc.contributor.author | Cantrill, Stuart J. | - |
dc.contributor.author | Stoddart, J. Fraser | - |
dc.date.accessioned | 2023-10-06T05:13:00Z | - |
dc.date.available | 2023-10-06T05:13:00Z | - |
dc.date.issued | 2005 | - |
dc.identifier.citation | Journal of Organic Chemistry, 2005, v. 70, n. 20, p. 7956-7962 | - |
dc.identifier.issn | 0022-3263 | - |
dc.identifier.uri | http://hdl.handle.net/10722/332626 | - |
dc.description.abstract | In addition to a parent zinc(II) Borromean ring (BR) complex, the preparation and characterization of two hexasubstituted BR complexes with either 4-acetoxymethylphenyl or 4-methylthiophenyl substituents associated in turn with all six pyridyl rings has been achieved convergently in good yields by appealing to the dynamic features of the reactions between primary amino groups in a preformed acyclic ligand and 2,6-diformylpyridine. Two molecules of the acyclic ligands react with two molecules of 2,6-diformylpyridine to form a cyclic [2 + 2] tetraimine in the presence of Zn(II) ions as templates in 2-propanol at 70 °C. The successful preparation of the two derivatives by convergent template-directed syntheses opens up opportunities to self-assemble, under equilibrium control, numerous nanoscale metallo-organic particles with potentially useful properties. © 2005 American Chemical Society. | - |
dc.language | eng | - |
dc.relation.ispartof | Journal of Organic Chemistry | - |
dc.title | Nanoscale borromeates | - |
dc.type | Article | - |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1021/jo050969b | - |
dc.identifier.scopus | eid_2-s2.0-25444487281 | - |
dc.identifier.volume | 70 | - |
dc.identifier.issue | 20 | - |
dc.identifier.spage | 7956 | - |
dc.identifier.epage | 7962 | - |
dc.identifier.isi | WOS:000232166800017 | - |