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Article: Slow shuttling in an amphiphilic bistable [2]rotaxane incorporating a tetrathiafulvalene unit

TitleSlow shuttling in an amphiphilic bistable [2]rotaxane incorporating a tetrathiafulvalene unit
Authors
KeywordsIsomerization
Rotaxanes
Self-assembly
Supramolecular chemistry
Tetrathiafulvalene
Issue Date2001
Citation
Angewandte Chemie - International Edition, 2001, v. 40, n. 7, p. 1216-1221 How to Cite?
AbstractSeparation of the two translational isomers by preparative thin-layer chromatography (see picture) and a kinetic study of their interconversion are possible when a central barrier is inserted between two stations on the rod section in the dumbbell component of a [2]rotaxane. This switchable [2]rotaxane incorporates a monopyrrolotetrathiafulvalene unit and a 1,5-dioxynaphthalene ring system within its rod section and the tetracationic cyclobis(paraquat-p-phenylene) as its ring component.
Persistent Identifierhttp://hdl.handle.net/10722/332491
ISSN
2021 Impact Factor: 16.823
2020 SCImago Journal Rankings: 5.831
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorJeppesen, Jan O.-
dc.contributor.authorPerkins, Julie-
dc.contributor.authorBecher, Jan-
dc.contributor.authorFraser Stoddart, J.-
dc.date.accessioned2023-10-06T05:11:55Z-
dc.date.available2023-10-06T05:11:55Z-
dc.date.issued2001-
dc.identifier.citationAngewandte Chemie - International Edition, 2001, v. 40, n. 7, p. 1216-1221-
dc.identifier.issn1433-7851-
dc.identifier.urihttp://hdl.handle.net/10722/332491-
dc.description.abstractSeparation of the two translational isomers by preparative thin-layer chromatography (see picture) and a kinetic study of their interconversion are possible when a central barrier is inserted between two stations on the rod section in the dumbbell component of a [2]rotaxane. This switchable [2]rotaxane incorporates a monopyrrolotetrathiafulvalene unit and a 1,5-dioxynaphthalene ring system within its rod section and the tetracationic cyclobis(paraquat-p-phenylene) as its ring component.-
dc.languageeng-
dc.relation.ispartofAngewandte Chemie - International Edition-
dc.subjectIsomerization-
dc.subjectRotaxanes-
dc.subjectSelf-assembly-
dc.subjectSupramolecular chemistry-
dc.subjectTetrathiafulvalene-
dc.titleSlow shuttling in an amphiphilic bistable [2]rotaxane incorporating a tetrathiafulvalene unit-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1002/1521-3773(20010401)40:7<1216::AID-ANIE1216>3.0.CO;2-W-
dc.identifier.scopuseid_2-s2.0-0035794906-
dc.identifier.volume40-
dc.identifier.issue7-
dc.identifier.spage1216-
dc.identifier.epage1221-
dc.identifier.isiWOS:000167941100009-

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