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Article: Synthesis of P-chiral phosphine compounds by palladium-catalyzed C–P coupling reactions

TitleSynthesis of P-chiral phosphine compounds by palladium-catalyzed C–P coupling reactions
Authors
Wang, CYue, CDYuan, JZheng, JLZhang, YYu, HChen, JMeng, SYu, YYu, GAChe, CM
Issue Date2020
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.asp
Citation
Chemical Communications, 2020, v. 56 n. 79, p. 11775-11778 How to Cite?
DOI: http://dx.doi.org/10.1039/D0CC05340F
AbstractAn efficient C–P coupling reaction of enantiopure tert-butylmethylphosphine-boranes with aryl and heteroaryl halides is developed by using Pd(OAc)2/dppf as a catalyst, affording a series of (S) or (R)-P-chiral phosphines in moderate to high yields and with ee values up to 99% ee. Moreover, the reaction time could be reduced from 72 h to 6 h with increased ee values under microwave irradiation.
Persistent Identifierhttp://hdl.handle.net/10722/302451
ISSN
1359-7345
2021 Impact Factor: 6.065
2020 SCImago Journal Rankings: 1.837
ISI Accession Number ID
WOS:000575366000037

 

DC FieldValueLanguage
dc.contributor.authorWang, C-
dc.contributor.authorYue, CD-
dc.contributor.authorYuan, J-
dc.contributor.authorZheng, JL-
dc.contributor.authorZhang, Y-
dc.contributor.authorYu, H-
dc.contributor.authorChen, J-
dc.contributor.authorMeng, S-
dc.contributor.authorYu, Y-
dc.contributor.authorYu, GA-
dc.contributor.authorChe, CM-
dc.date.accessioned2021-09-06T03:32:29Z-
dc.date.available2021-09-06T03:32:29Z-
dc.date.issued2020-
dc.identifier.citationChemical Communications, 2020, v. 56 n. 79, p. 11775-11778-
dc.identifier.issn1359-7345-
dc.identifier.urihttp://hdl.handle.net/10722/302451-
dc.description.abstractAn efficient C–P coupling reaction of enantiopure tert-butylmethylphosphine-boranes with aryl and heteroaryl halides is developed by using Pd(OAc)2/dppf as a catalyst, affording a series of (S) or (R)-P-chiral phosphines in moderate to high yields and with ee values up to 99% ee. Moreover, the reaction time could be reduced from 72 h to 6 h with increased ee values under microwave irradiation.-
dc.languageeng-
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.asp-
dc.relation.ispartofChemical Communications-
dc.titleSynthesis of P-chiral phosphine compounds by palladium-catalyzed C–P coupling reactions-
dc.typeArticle-
dc.identifier.emailChe, CM: chemhead@hku.hk-
dc.identifier.authorityChe, CM=rp00670-
dc.description.naturepostprint-
dc.identifier.doi10.1039/D0CC05340F-
dc.identifier.pmid32909558-
dc.identifier.scopuseid_2-s2.0-85092233604-
dc.identifier.hkuros324863-
dc.identifier.volume56-
dc.identifier.issue79-
dc.identifier.spage11775-
dc.identifier.epage11778-
dc.identifier.isiWOS:000575366000037-
dc.publisher.placeUnited Kingdom-

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