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- Publisher Website: 10.1039/D0SC01340D
- Scopus: eid_2-s2.0-85087781901
- PMID: 32874518
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Article: Luminescent Tungsten(vi) Complexes As Photocatalysts For Light-driven C–c And C–b Bond Formation Reactions
Title | Luminescent Tungsten(vi) Complexes As Photocatalysts For Light-driven C–c And C–b Bond Formation Reactions |
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Authors | |
Keywords | Chemical bonds Chlorine compounds Light Photochemical reactions Redox reactions |
Issue Date | 2020 |
Publisher | Royal Society of Chemistry: Open Access. The Journal's web site is located at http://www.rsc.org/publishing/journals/sc/About.asp |
Citation | Chemical Science, 2020, v. 11 n. 25, p. 6370-6382 How to Cite? |
Abstract | The realization of photocatalysis for practical synthetic application hinges on the development of inexpensive photocatalysts which can be prepared on a large scale. Herein an air-stable, visible-lightabsorbing photoluminescent tungsten(VI) complex which can be conveniently prepared at the gramscale is described. This complex could catalyse photochemical organic transformation reactions including borylation of aryl halides, such as aryl chloride, reductive coupling of benzyl bromides for C–C bond formation, reductive coupling of phenacyl bromides, and decarboxylative coupling of redox-active esters of alkyl carboxylic acid with high product yields and broad functional group tolerance. |
Persistent Identifier | http://hdl.handle.net/10722/286160 |
ISSN | 2023 Impact Factor: 7.6 2023 SCImago Journal Rankings: 2.333 |
PubMed Central ID | |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Yu, D | - |
dc.contributor.author | To, WP | - |
dc.contributor.author | Tong, GSM | - |
dc.contributor.author | Wu, LL | - |
dc.contributor.author | Chan, KT | - |
dc.contributor.author | Du, L | - |
dc.contributor.author | Phillips, DL | - |
dc.contributor.author | Liu, Y | - |
dc.contributor.author | Che, CM | - |
dc.date.accessioned | 2020-08-31T06:59:58Z | - |
dc.date.available | 2020-08-31T06:59:58Z | - |
dc.date.issued | 2020 | - |
dc.identifier.citation | Chemical Science, 2020, v. 11 n. 25, p. 6370-6382 | - |
dc.identifier.issn | 2041-6520 | - |
dc.identifier.uri | http://hdl.handle.net/10722/286160 | - |
dc.description.abstract | The realization of photocatalysis for practical synthetic application hinges on the development of inexpensive photocatalysts which can be prepared on a large scale. Herein an air-stable, visible-lightabsorbing photoluminescent tungsten(VI) complex which can be conveniently prepared at the gramscale is described. This complex could catalyse photochemical organic transformation reactions including borylation of aryl halides, such as aryl chloride, reductive coupling of benzyl bromides for C–C bond formation, reductive coupling of phenacyl bromides, and decarboxylative coupling of redox-active esters of alkyl carboxylic acid with high product yields and broad functional group tolerance. | - |
dc.language | eng | - |
dc.publisher | Royal Society of Chemistry: Open Access. The Journal's web site is located at http://www.rsc.org/publishing/journals/sc/About.asp | - |
dc.relation.ispartof | Chemical Science | - |
dc.rights | This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License. | - |
dc.subject | Chemical bonds | - |
dc.subject | Chlorine compounds | - |
dc.subject | Light | - |
dc.subject | Photochemical reactions | - |
dc.subject | Redox reactions | - |
dc.title | Luminescent Tungsten(vi) Complexes As Photocatalysts For Light-driven C–c And C–b Bond Formation Reactions | - |
dc.type | Article | - |
dc.identifier.email | Yu, D: yudh123@hku.hk | - |
dc.identifier.email | To, WP: kevintwp@hku.hk | - |
dc.identifier.email | Tong, GSM: tongsm@hku.hk | - |
dc.identifier.email | Wu, LL: llwusx@hku.hk | - |
dc.identifier.email | Du, L: ailleen@hku.hk | - |
dc.identifier.email | Phillips, DL: phillips@hku.hk | - |
dc.identifier.email | Che, CM: chemhead@hku.hk | - |
dc.identifier.authority | To, WP=rp02410 | - |
dc.identifier.authority | Tong, GSM=rp00790 | - |
dc.identifier.authority | Phillips, DL=rp00770 | - |
dc.identifier.authority | Che, CM=rp00670 | - |
dc.description.nature | published_or_final_version | - |
dc.identifier.doi | 10.1039/D0SC01340D | - |
dc.identifier.pmid | 32874518 | - |
dc.identifier.pmcid | PMC7448528 | - |
dc.identifier.scopus | eid_2-s2.0-85087781901 | - |
dc.identifier.hkuros | 313156 | - |
dc.identifier.volume | 11 | - |
dc.identifier.issue | 25 | - |
dc.identifier.spage | 6370 | - |
dc.identifier.epage | 6382 | - |
dc.identifier.isi | WOS:000544484900023 | - |
dc.publisher.place | United Kingdom | - |
dc.identifier.issnl | 2041-6520 | - |