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Article: Intramolecular Nitrene Insertion into Saturated C-H-Bond-Mediated C-N Bond Cleavage of a Coordinated NHC Ligand

TitleIntramolecular Nitrene Insertion into Saturated C-H-Bond-Mediated C-N Bond Cleavage of a Coordinated NHC Ligand
Authors
KeywordsC−N bond activation
N-heterocyclic carbenes
nitrene transfer reactions
N ligands
ruthenium
Issue Date2019
PublisherWiley - VCH Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www.wiley-vch.de/home/chemistry
Citation
Chemistry - A European Journal, 2019, v. 25 n. 46, p. 10828-10833 How to Cite?
AbstractRuthenium(II) complexes bearing a tridentate bis(N-heterocyclic carbene) ligand reacted with iminoiodanes (PhI=NR) resulting in the formation of isolable ruthenium(III)–amido intermediates, which underwent cleavage of a C-N bond of the tridentate ligand and formation of an N-substituted imine group. The Ru(III)–amido intermediates have been characterized by 1H NMR, UV/Vis, ESI-MS, and X-ray crystallography. DFT calculations were performed to provide insight into the reaction mechanism.
Persistent Identifierhttp://hdl.handle.net/10722/278118
ISSN
2017 Impact Factor: 5.16
2015 SCImago Journal Rankings: 2.323

 

DC FieldValueLanguage
dc.contributor.authorLiu, Y-
dc.contributor.authorTse, CW-
dc.contributor.authorLAM, KY-
dc.contributor.authorChang, XY-
dc.contributor.authorGuan, X-
dc.contributor.authorChao, MY-
dc.contributor.authorHuang, JS-
dc.contributor.authorChe, CM-
dc.date.accessioned2019-10-04T08:07:50Z-
dc.date.available2019-10-04T08:07:50Z-
dc.date.issued2019-
dc.identifier.citationChemistry - A European Journal, 2019, v. 25 n. 46, p. 10828-10833-
dc.identifier.issn0947-6539-
dc.identifier.urihttp://hdl.handle.net/10722/278118-
dc.description.abstractRuthenium(II) complexes bearing a tridentate bis(N-heterocyclic carbene) ligand reacted with iminoiodanes (PhI=NR) resulting in the formation of isolable ruthenium(III)–amido intermediates, which underwent cleavage of a C-N bond of the tridentate ligand and formation of an N-substituted imine group. The Ru(III)–amido intermediates have been characterized by 1H NMR, UV/Vis, ESI-MS, and X-ray crystallography. DFT calculations were performed to provide insight into the reaction mechanism.-
dc.languageeng-
dc.publisherWiley - VCH Verlag GmbH & Co. KGaA. The Journal's web site is located at http://www.wiley-vch.de/home/chemistry-
dc.relation.ispartofChemistry - A European Journal-
dc.rightsThis is the peer reviewed version of the following article: [FULL CITE], which has been published in final form at [Link to final article using the DOI]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.-
dc.subjectC−N bond activation-
dc.subjectN-heterocyclic carbenes-
dc.subjectnitrene transfer reactions-
dc.subjectN ligands-
dc.subjectruthenium-
dc.titleIntramolecular Nitrene Insertion into Saturated C-H-Bond-Mediated C-N Bond Cleavage of a Coordinated NHC Ligand-
dc.typeArticle-
dc.identifier.emailGuan, X: xgguan@hku.hk-
dc.identifier.emailHuang, JS: jshuang@hku.hk-
dc.identifier.emailChe, CM: chemhead@hku.hk-
dc.identifier.authorityHuang, JS=rp00709-
dc.identifier.authorityChe, CM=rp00670-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1002/chem.201903012-
dc.identifier.pmid31271674-
dc.identifier.scopuseid_2-s2.0-85070849287-
dc.identifier.hkuros306316-
dc.identifier.volume25-
dc.identifier.issue46-
dc.identifier.spage10828-
dc.identifier.epage10833-
dc.publisher.placeGermany-

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