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- Publisher Website: 10.1002/anie.201610426
- Scopus: eid_2-s2.0-85010888074
- PMID: 28078773
- WOS: WOS:000395554900030
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Article: Ligand-Enabled Alkynylation of C(sp3)−H Bonds with Palladium(II) Catalysts
| Title | Ligand-Enabled Alkynylation of C(sp3)−H Bonds with Palladium(II) Catalysts |
|---|---|
| Authors | |
| Keywords | alkynylation pyridine palladium C−H activation amino acids |
| Issue Date | 2017 |
| Citation | Angewandte Chemie - International Edition, 2017, v. 56, n. 7, p. 1873-1876 How to Cite? |
| Abstract | © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim The palladium(II)-catalyzed β- and γ-alkynylation of amide C(sp3)−H bonds is enabled by pyridine-based ligands. This alkynylation reaction is compatible with substrates containing α-tertiary or α-quaternary carbon centers. The β-methylene C(sp3)−H bonds of various carbocyclic rings were also successfully alkynylated. |
| Persistent Identifier | http://hdl.handle.net/10722/277056 |
| ISSN | 2021 Impact Factor: 16.823 2020 SCImago Journal Rankings: 5.831 |
| ISI Accession Number ID |
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Fu, Haiyan | - |
| dc.contributor.author | Shen, Peng Xiang | - |
| dc.contributor.author | He, Jian | - |
| dc.contributor.author | Zhang, Fanglin | - |
| dc.contributor.author | Li, Suhua | - |
| dc.contributor.author | Wang, Peng | - |
| dc.contributor.author | Liu, Tao | - |
| dc.contributor.author | Yu, Jin Quan | - |
| dc.date.accessioned | 2019-09-18T08:35:28Z | - |
| dc.date.available | 2019-09-18T08:35:28Z | - |
| dc.date.issued | 2017 | - |
| dc.identifier.citation | Angewandte Chemie - International Edition, 2017, v. 56, n. 7, p. 1873-1876 | - |
| dc.identifier.issn | 1433-7851 | - |
| dc.identifier.uri | http://hdl.handle.net/10722/277056 | - |
| dc.description.abstract | © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim The palladium(II)-catalyzed β- and γ-alkynylation of amide C(sp3)−H bonds is enabled by pyridine-based ligands. This alkynylation reaction is compatible with substrates containing α-tertiary or α-quaternary carbon centers. The β-methylene C(sp3)−H bonds of various carbocyclic rings were also successfully alkynylated. | - |
| dc.language | eng | - |
| dc.relation.ispartof | Angewandte Chemie - International Edition | - |
| dc.subject | alkynylation | - |
| dc.subject | pyridine | - |
| dc.subject | palladium | - |
| dc.subject | C−H activation | - |
| dc.subject | amino acids | - |
| dc.title | Ligand-Enabled Alkynylation of C(sp3)−H Bonds with Palladium(II) Catalysts | - |
| dc.type | Article | - |
| dc.description.nature | link_to_subscribed_fulltext | - |
| dc.identifier.doi | 10.1002/anie.201610426 | - |
| dc.identifier.pmid | 28078773 | - |
| dc.identifier.scopus | eid_2-s2.0-85010888074 | - |
| dc.identifier.volume | 56 | - |
| dc.identifier.issue | 7 | - |
| dc.identifier.spage | 1873 | - |
| dc.identifier.epage | 1876 | - |
| dc.identifier.eissn | 1521-3773 | - |
| dc.identifier.isi | WOS:000395554900030 | - |
| dc.identifier.issnl | 1433-7851 | - |