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Article: Continuous-Flow Synthesis of Supported Magnetic Iron Oxide Nanoparticles for Efficient Isoeugenol Conversion into Vanillin

TitleContinuous-Flow Synthesis of Supported Magnetic Iron Oxide Nanoparticles for Efficient Isoeugenol Conversion into Vanillin
Authors
Keywordsiron oxide
isoeugenol
nanoparticles
oxidation
vanillin
Issue Date2018
PublisherWiley - V C H Verlag GmbH & Co. KGaA. The Journal's web site is located at https://onlinelibrary.wiley.com/journal/1864564x
Citation
ChemSusChem, 2018, v. 11 n. 2, p. 389-396 How to Cite?
AbstractThis work presents the synthesis of iron oxide nanocatalysts supported on mesoporous Al-SBA-15 by using a continuous-flow setup. The magnetic nanomaterials were tested as catalysts in the oxidative disruption of isoeugenol by using hydrogen peroxide as a green oxidant, featuring high activities (63–88 % conversion) and good selectivities to vanillin (44–68 %). The catalytic systems exhibited good magnetic properties when synthesized under continuous-flow conditions at temperatures not exceeding 190 °C. The use of microwave irradiation significantly reduced times of reaction drastically but exerted negative effects on catalyst reusability. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
Persistent Identifierhttp://hdl.handle.net/10722/274863
ISSN
2017 Impact Factor: 7.411
2015 SCImago Journal Rankings: 2.649
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorMarquez‐Medina, MD-
dc.contributor.authorPrinsen, P-
dc.contributor.authorLi, H-
dc.contributor.authorShih, K-
dc.contributor.authorRomero, AA-
dc.contributor.authorLuque, R-
dc.date.accessioned2019-09-10T02:30:27Z-
dc.date.available2019-09-10T02:30:27Z-
dc.date.issued2018-
dc.identifier.citationChemSusChem, 2018, v. 11 n. 2, p. 389-396-
dc.identifier.issn1864-5631-
dc.identifier.urihttp://hdl.handle.net/10722/274863-
dc.description.abstractThis work presents the synthesis of iron oxide nanocatalysts supported on mesoporous Al-SBA-15 by using a continuous-flow setup. The magnetic nanomaterials were tested as catalysts in the oxidative disruption of isoeugenol by using hydrogen peroxide as a green oxidant, featuring high activities (63–88 % conversion) and good selectivities to vanillin (44–68 %). The catalytic systems exhibited good magnetic properties when synthesized under continuous-flow conditions at temperatures not exceeding 190 °C. The use of microwave irradiation significantly reduced times of reaction drastically but exerted negative effects on catalyst reusability. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim-
dc.languageeng-
dc.publisherWiley - V C H Verlag GmbH & Co. KGaA. The Journal's web site is located at https://onlinelibrary.wiley.com/journal/1864564x-
dc.relation.ispartofChemSusChem-
dc.subjectiron oxide-
dc.subjectisoeugenol-
dc.subjectnanoparticles-
dc.subjectoxidation-
dc.subjectvanillin-
dc.titleContinuous-Flow Synthesis of Supported Magnetic Iron Oxide Nanoparticles for Efficient Isoeugenol Conversion into Vanillin-
dc.typeArticle-
dc.identifier.emailShih, K: kshih@hku.hk-
dc.identifier.authorityShih, K=rp00167-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1002/cssc.201701884-
dc.identifier.pmid29161467-
dc.identifier.scopuseid_2-s2.0-85039172158-
dc.identifier.hkuros303525-
dc.identifier.volume11-
dc.identifier.issue2-
dc.identifier.spage389-
dc.identifier.epage396-
dc.identifier.isiWOS:000423205200006-
dc.publisher.placeGermany-

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