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- Publisher Website: 10.1039/c8cc10220a
- Scopus: eid_2-s2.0-85063224044
- PMID: 30843908
- WOS: WOS:000463755900005
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Article: Stable iridium(IV) complexes supported by tetradentate salen ligands. Synthesis, structures and reactivity
Title | Stable iridium(IV) complexes supported by tetradentate salen ligands. Synthesis, structures and reactivity |
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Authors | |
Issue Date | 2019 |
Publisher | Royal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.asp |
Citation | Chemical Communications, 2019, v. 55 n. 25, p. 3606-3609 How to Cite? |
Abstract | A series of trans-dichloroiridium(IV)–salen complexes were synthesized and structurally characterized by spectroscopic means and Xray crystal structures. These Ir(IV) complexes are able to catalyze intramolecular C–H amination of aryl azides. The catalytic amination was drastically accelerated under microwave-assisted conditions, and possibly involves Ir-imido intermediates as supported by high-resolution ESI-MS analysis. |
Persistent Identifier | http://hdl.handle.net/10722/269419 |
ISSN | 2023 Impact Factor: 4.3 2023 SCImago Journal Rankings: 1.133 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Lee, CL | - |
dc.contributor.author | Wu, L | - |
dc.contributor.author | Huang, JS | - |
dc.contributor.author | Che, CM | - |
dc.date.accessioned | 2019-04-24T08:07:19Z | - |
dc.date.available | 2019-04-24T08:07:19Z | - |
dc.date.issued | 2019 | - |
dc.identifier.citation | Chemical Communications, 2019, v. 55 n. 25, p. 3606-3609 | - |
dc.identifier.issn | 1359-7345 | - |
dc.identifier.uri | http://hdl.handle.net/10722/269419 | - |
dc.description.abstract | A series of trans-dichloroiridium(IV)–salen complexes were synthesized and structurally characterized by spectroscopic means and Xray crystal structures. These Ir(IV) complexes are able to catalyze intramolecular C–H amination of aryl azides. The catalytic amination was drastically accelerated under microwave-assisted conditions, and possibly involves Ir-imido intermediates as supported by high-resolution ESI-MS analysis. | - |
dc.language | eng | - |
dc.publisher | Royal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.asp | - |
dc.relation.ispartof | Chemical Communications | - |
dc.rights | © The Royal Society of Chemistry 2019. The final published version is available online at https://doi.org/10.1039/C8CC10220A | - |
dc.title | Stable iridium(IV) complexes supported by tetradentate salen ligands. Synthesis, structures and reactivity | - |
dc.type | Article | - |
dc.identifier.email | Lee, CL: mrcllee@connect.hku.hk | - |
dc.identifier.email | Wu, L: llwusx@hku.hk | - |
dc.identifier.email | Huang, JS: jshuang@hku.hk | - |
dc.identifier.email | Che, CM: chemhead@hku.hk | - |
dc.identifier.authority | Huang, JS=rp00709 | - |
dc.identifier.authority | Che, CM=rp00670 | - |
dc.description.nature | postprint | - |
dc.identifier.doi | 10.1039/c8cc10220a | - |
dc.identifier.pmid | 30843908 | - |
dc.identifier.scopus | eid_2-s2.0-85063224044 | - |
dc.identifier.hkuros | 297578 | - |
dc.identifier.volume | 55 | - |
dc.identifier.issue | 25 | - |
dc.identifier.spage | 3606 | - |
dc.identifier.epage | 3609 | - |
dc.identifier.isi | WOS:000463755900005 | - |
dc.publisher.place | United Kingdom | - |
dc.identifier.issnl | 1359-7345 | - |