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Article: Controllable synthesis of carbon nanosheets derived from oxidative polymerisation of m-phenylenediamine

TitleControllable synthesis of carbon nanosheets derived from oxidative polymerisation of m-phenylenediamine
Authors
KeywordsCarbon nanosheets
Oxidative polymerisation
Poly(m-phenylenediamine)
Porosity
Issue Date2019
PublisherAcademic Press. The Journal's web site is located at http://www.elsevier.com/locate/jcis
Citation
Journal of Colloid and Interface Science, 2019, v. 533, p. 437-444 How to Cite?
AbstractSynthesis of high-quality carbon nanosheets with superior physicochemical properties is of particular importance for environmental and catalytic applications. In this research, carbon nanosheets with tunable porosity were successfully synthesized using two-dimensional (2D) poly(m-phenylenediamine) (PmPD) as precursor. The flat polymer precursor was acquired by oxidative polymerisation of m-phenylenediamine coupled with iron ions coordination, which confined an anisotropic growth of polymer within the 2D directions. Moreover, the addition of H2O after the polymerisation is able to indirectly regulate the porosity of the carbon nanosheets. The carbon nanosheets with controllable porosity realize comparable electrocatalytic activity for oxygen reduction reaction as compared with commercial Pt/C, indicative of great potential to serve as noble metals candidates in the application of zinc/air batteries.
Persistent Identifierhttp://hdl.handle.net/10722/260389
ISSN
2017 Impact Factor: 5.091
2015 SCImago Journal Rankings: 1.126

 

DC FieldValueLanguage
dc.contributor.authorZhang, L-
dc.contributor.authorChai, L-
dc.contributor.authorWang, M-
dc.contributor.authorLai, Y-
dc.contributor.authorLai, Y-
dc.contributor.authorLi, XY-
dc.date.accessioned2018-09-14T08:40:56Z-
dc.date.available2018-09-14T08:40:56Z-
dc.date.issued2019-
dc.identifier.citationJournal of Colloid and Interface Science, 2019, v. 533, p. 437-444-
dc.identifier.issn0021-9797-
dc.identifier.urihttp://hdl.handle.net/10722/260389-
dc.description.abstractSynthesis of high-quality carbon nanosheets with superior physicochemical properties is of particular importance for environmental and catalytic applications. In this research, carbon nanosheets with tunable porosity were successfully synthesized using two-dimensional (2D) poly(m-phenylenediamine) (PmPD) as precursor. The flat polymer precursor was acquired by oxidative polymerisation of m-phenylenediamine coupled with iron ions coordination, which confined an anisotropic growth of polymer within the 2D directions. Moreover, the addition of H2O after the polymerisation is able to indirectly regulate the porosity of the carbon nanosheets. The carbon nanosheets with controllable porosity realize comparable electrocatalytic activity for oxygen reduction reaction as compared with commercial Pt/C, indicative of great potential to serve as noble metals candidates in the application of zinc/air batteries.-
dc.languageeng-
dc.publisherAcademic Press. The Journal's web site is located at http://www.elsevier.com/locate/jcis-
dc.relation.ispartofJournal of Colloid and Interface Science-
dc.subjectCarbon nanosheets-
dc.subjectOxidative polymerisation-
dc.subjectPoly(m-phenylenediamine)-
dc.subjectPorosity-
dc.titleControllable synthesis of carbon nanosheets derived from oxidative polymerisation of m-phenylenediamine-
dc.typeArticle-
dc.identifier.emailZhang, L: lyzhk@hku.hk-
dc.identifier.emailLi, XY: xlia@hkucc.hku.hk-
dc.identifier.authorityLi, XY=rp00222-
dc.description.naturelink_to_OA_fulltext-
dc.identifier.doi10.1016/j.jcis.2018.08.101-
dc.identifier.pmid30172154-
dc.identifier.scopuseid_2-s2.0-85052441128-
dc.identifier.hkuros290332-
dc.identifier.volume533-
dc.identifier.spage437-
dc.identifier.epage444-
dc.publisher.placeUnited States-

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