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Article: Structure and photoluminescence of cubane-like [Cu 4 I 4 ] cluster-based 1D coordination polymer assembled with bis(triazole)pyridine ligand

TitleStructure and photoluminescence of cubane-like [Cu 4 I 4 ] cluster-based 1D coordination polymer assembled with bis(triazole)pyridine ligand
Authors
KeywordsBis(triazole) ligand
Cubane-like [Cu4I4] cluster
Coordination polymer
Luminescence
Issue Date2017
PublisherElsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchem
Citation
Journal of Organometallic Chemistry, 2017, v. 849-850, p. 137-141 How to Cite?
Abstract[L2Cu4I4]n (1) based on a cubic [Cu4I4] node and ditopic, bridging bis(triazole) (L = 2,6-bis((1H-1,2,3-triazol-1-yl)methyl)pyridine) is a unique and highly symmetric cubane cluster based coordination polymer with strong yellow emission. Comparison with similar coordination polymers permits a structure activity relationship and reveals that the emission energy for these [Cu4I4] cluster-based materials occurs in the mid-range of Cu⋅⋅⋅Cu distances and tetrahedral geometry index values.
Persistent Identifierhttp://hdl.handle.net/10722/254780
ISSN
2015 Impact Factor: 2.336
2015 SCImago Journal Rankings: 0.732

 

DC FieldValueLanguage
dc.contributor.authorBai, SQ-
dc.contributor.authorKe, KL-
dc.contributor.authorYoung, DJ-
dc.contributor.authorHor, TSA-
dc.date.accessioned2018-06-21T01:06:28Z-
dc.date.available2018-06-21T01:06:28Z-
dc.date.issued2017-
dc.identifier.citationJournal of Organometallic Chemistry, 2017, v. 849-850, p. 137-141-
dc.identifier.issn0022-328X-
dc.identifier.urihttp://hdl.handle.net/10722/254780-
dc.description.abstract[L2Cu4I4]n (1) based on a cubic [Cu4I4] node and ditopic, bridging bis(triazole) (L = 2,6-bis((1H-1,2,3-triazol-1-yl)methyl)pyridine) is a unique and highly symmetric cubane cluster based coordination polymer with strong yellow emission. Comparison with similar coordination polymers permits a structure activity relationship and reveals that the emission energy for these [Cu4I4] cluster-based materials occurs in the mid-range of Cu⋅⋅⋅Cu distances and tetrahedral geometry index values.-
dc.languageeng-
dc.publisherElsevier SA. The Journal's web site is located at http://www.elsevier.com/locate/jorganchem-
dc.relation.ispartofJournal of Organometallic Chemistry-
dc.subjectBis(triazole) ligand-
dc.subjectCubane-like [Cu4I4] cluster-
dc.subjectCoordination polymer-
dc.subjectLuminescence-
dc.titleStructure and photoluminescence of cubane-like [Cu 4 I 4 ] cluster-based 1D coordination polymer assembled with bis(triazole)pyridine ligand-
dc.typeArticle-
dc.identifier.emailHor, TSA: andyhor@hku.hk-
dc.identifier.authorityHor, TSA=rp02077-
dc.identifier.doi10.1016/j.jorganchem.2017.03.040-
dc.identifier.hkuros285664-
dc.identifier.volume849-850-
dc.identifier.spage137-
dc.identifier.epage141-
dc.publisher.placeSwitzerland-

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