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Article: Sequential growth of heteropolymetallic (Pt-2->AgPt2-> Ag2Pt2->Ag2Pt4) sulfide aggregates. Structure of the intermediate Ag2Pt2Cl2(PPh3)(4)(mu(3)-S)(2) with a flat {Pt2S2} core and two AgCl molecular pendants

TitleSequential growth of heteropolymetallic (Pt-2->AgPt2-> Ag2Pt2->Ag2Pt4) sulfide aggregates. Structure of the intermediate Ag2Pt2Cl2(PPh3)(4)(mu(3)-S)(2) with a flat {Pt2S2} core and two AgCl molecular pendants
Authors
Issue Date1997
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/ic
Citation
Inorganic Chemistry, 1997, v. 36 n. 13, p. 2916 How to Cite?
AbstractConversion of Pt-2(PPh3)(4)(mu-S)(2) to [Ag-2{Pt-2(PPh3)(4)(mu-S)(2)}(2)](2+) via [AgPt2(PPh3)(5)(mu(3)-S)(2)](+) and Ag2Pt2Cl2(PPh3)(4)(mu(3)-S)(2) demonstrates an aggregate growth process whereby stepwise addition of Ag+ and the Pt-2 metalloligand is accompanied by a sequential unfolding and folding of the {Pt2S2} butterfly core.
Persistent Identifierhttp://hdl.handle.net/10722/237655
ISSN
2015 Impact Factor: 4.82
2015 SCImago Journal Rankings: 1.873
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorLiu, H-
dc.contributor.authorTan, AL-
dc.contributor.authorCheng, CR-
dc.contributor.authorMok, KF-
dc.contributor.authorHor, TSA-
dc.date.accessioned2017-01-17T07:52:47Z-
dc.date.available2017-01-17T07:52:47Z-
dc.date.issued1997-
dc.identifier.citationInorganic Chemistry, 1997, v. 36 n. 13, p. 2916-
dc.identifier.issn0020-1669-
dc.identifier.urihttp://hdl.handle.net/10722/237655-
dc.description.abstractConversion of Pt-2(PPh3)(4)(mu-S)(2) to [Ag-2{Pt-2(PPh3)(4)(mu-S)(2)}(2)](2+) via [AgPt2(PPh3)(5)(mu(3)-S)(2)](+) and Ag2Pt2Cl2(PPh3)(4)(mu(3)-S)(2) demonstrates an aggregate growth process whereby stepwise addition of Ag+ and the Pt-2 metalloligand is accompanied by a sequential unfolding and folding of the {Pt2S2} butterfly core.-
dc.languageeng-
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/ic-
dc.relation.ispartofInorganic Chemistry-
dc.titleSequential growth of heteropolymetallic (Pt-2->AgPt2-> Ag2Pt2->Ag2Pt4) sulfide aggregates. Structure of the intermediate Ag2Pt2Cl2(PPh3)(4)(mu(3)-S)(2) with a flat {Pt2S2} core and two AgCl molecular pendants-
dc.typeArticle-
dc.identifier.emailHor, TSA: andyhor@hku.hk-
dc.identifier.authorityHor, TSA=rp02077-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/ic961173l-
dc.identifier.volume36-
dc.identifier.issue13-
dc.identifier.spage2916-
dc.identifier.epage2916-
dc.identifier.isiWOS:A1997XF30900038-
dc.publisher.placeUnited States-

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