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Article: New solid-state Eu(III)-containing metallo-supramolecular polymers: Morphology control and optical wave-guiding properties
Title | New solid-state Eu(III)-containing metallo-supramolecular polymers: Morphology control and optical wave-guiding properties |
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Authors | |
Issue Date | 2015 |
Citation | Journal of Materials Chemistry C, 2015, v. 3, n. 34, p. 8992-9002 How to Cite? |
Abstract | © The Royal Society of Chemistry 2015.Herein, we report the solution phase self-assembly between Eu(iii) and a rigid ditopic tridentate terpyridine ligand which results in the formation of supramolecular metallo-networks in the solid state. Depending on the ligand to metal ratio used for the initial self-assembly process, the morphology of these materials can be altered from one-dimensional micron-sized fibres to a three-dimensional coordination network. The terpyridine-based ditopic ligand can act as an efficient sensitizer for Eu(iii) emission whereby the emission lifetimes and ligand triplet state energies of the metallo-polymers strongly depend on the ligand to metal ratio. The obtained micron-sized fibres can act as an efficient optical wave-guide for Eu(iii) emission. |
Persistent Identifier | http://hdl.handle.net/10722/237629 |
ISSN | 2023 Impact Factor: 5.7 2023 SCImago Journal Rankings: 1.358 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Duerrbeck, Andre | - |
dc.contributor.author | Gorelik, Sergey | - |
dc.contributor.author | Hobley, Jonathan | - |
dc.contributor.author | Yong, Anna Marie | - |
dc.contributor.author | Subramanian, Gomathy Sandhya | - |
dc.contributor.author | Hor, Andy | - |
dc.contributor.author | Long, Nicholas | - |
dc.date.accessioned | 2017-01-16T06:10:19Z | - |
dc.date.available | 2017-01-16T06:10:19Z | - |
dc.date.issued | 2015 | - |
dc.identifier.citation | Journal of Materials Chemistry C, 2015, v. 3, n. 34, p. 8992-9002 | - |
dc.identifier.issn | 2050-7534 | - |
dc.identifier.uri | http://hdl.handle.net/10722/237629 | - |
dc.description.abstract | © The Royal Society of Chemistry 2015.Herein, we report the solution phase self-assembly between Eu(iii) and a rigid ditopic tridentate terpyridine ligand which results in the formation of supramolecular metallo-networks in the solid state. Depending on the ligand to metal ratio used for the initial self-assembly process, the morphology of these materials can be altered from one-dimensional micron-sized fibres to a three-dimensional coordination network. The terpyridine-based ditopic ligand can act as an efficient sensitizer for Eu(iii) emission whereby the emission lifetimes and ligand triplet state energies of the metallo-polymers strongly depend on the ligand to metal ratio. The obtained micron-sized fibres can act as an efficient optical wave-guide for Eu(iii) emission. | - |
dc.language | eng | - |
dc.relation.ispartof | Journal of Materials Chemistry C | - |
dc.title | New solid-state Eu(III)-containing metallo-supramolecular polymers: Morphology control and optical wave-guiding properties | - |
dc.type | Article | - |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1039/c5tc01703c | - |
dc.identifier.scopus | eid_2-s2.0-84939804489 | - |
dc.identifier.volume | 3 | - |
dc.identifier.issue | 34 | - |
dc.identifier.spage | 8992 | - |
dc.identifier.epage | 9002 | - |
dc.identifier.eissn | 2050-7526 | - |
dc.identifier.isi | WOS:000360120400032 | - |
dc.identifier.issnl | 2050-7526 | - |