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Article: Luminescent [Cu4I4] aggregates and [Cu3I3]-cyclic coordination polymers supported by quinolyl-triazoles
Title | Luminescent [Cu4I4] aggregates and [Cu3I3]-cyclic coordination polymers supported by quinolyl-triazoles |
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Authors | |
Issue Date | 2015 |
Citation | Dalton Transactions, 2015, v. 44, n. 13, p. 6075-6081 How to Cite? |
Abstract | © The Royal Society of Chemistry 2015.Quinolyl-1,2,3-triazole ligand supported [Cu4I4] stair-step aggregates [Cu4I4(L1)2] (1), [Cu4I4(L2)2] (2), [Cu4I4(L3)2] (3), [Cu4I4(L4)2] (4), [Cu4I4(L5)2] (5), and six-membered [Cu3I3] metallacycle based coordination polymers [Cu2I2(L6)]n (6) and [Cu2I2(L7)]n (7) (ligands are 2-((1H-1,2,3-triazol-1-yl)methyl)quinoline (L1), 2-((4-alkyl-1H-1,2,3-triazol-1-yl)methyl)quinoline (propyl, butyl and isobutyl for L2, L3 and L4, respectively) and 2-(1-((quinolin-2-yl)methyl)-1H-1,2,3-triazol-4-yl)alcohol (methanol, ethanol and propanol for L5, L6 and L7, respectively)) have been prepared and characterized by single-crystal X-ray diffraction (XRD), powder XRD, photoluminescence spectroscopy and thermogravimetric analysis. Complexes 1-5 are stair-step [Cu4I4] aggregate structures supported by two quinolyl-triazole hybrid ligands. Complexes 6 and 7 are rare cyclic [Cu3I3] aggregate-based 1-D coordination polymers. All ligands adopt a common tridentate-bridging coordination mode. These complexes are strongly luminescent with a yellow emission (500-700 nm) in the solid state. This journal is |
Persistent Identifier | http://hdl.handle.net/10722/237623 |
ISSN | 2023 Impact Factor: 3.5 2023 SCImago Journal Rankings: 0.697 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Bai, Shi Qiang | - |
dc.contributor.author | Jiang, Lu | - |
dc.contributor.author | Young, David James | - |
dc.contributor.author | Hor, T. S Andy | - |
dc.date.accessioned | 2017-01-16T06:10:16Z | - |
dc.date.available | 2017-01-16T06:10:16Z | - |
dc.date.issued | 2015 | - |
dc.identifier.citation | Dalton Transactions, 2015, v. 44, n. 13, p. 6075-6081 | - |
dc.identifier.issn | 1477-9226 | - |
dc.identifier.uri | http://hdl.handle.net/10722/237623 | - |
dc.description.abstract | © The Royal Society of Chemistry 2015.Quinolyl-1,2,3-triazole ligand supported [Cu4I4] stair-step aggregates [Cu4I4(L1)2] (1), [Cu4I4(L2)2] (2), [Cu4I4(L3)2] (3), [Cu4I4(L4)2] (4), [Cu4I4(L5)2] (5), and six-membered [Cu3I3] metallacycle based coordination polymers [Cu2I2(L6)]n (6) and [Cu2I2(L7)]n (7) (ligands are 2-((1H-1,2,3-triazol-1-yl)methyl)quinoline (L1), 2-((4-alkyl-1H-1,2,3-triazol-1-yl)methyl)quinoline (propyl, butyl and isobutyl for L2, L3 and L4, respectively) and 2-(1-((quinolin-2-yl)methyl)-1H-1,2,3-triazol-4-yl)alcohol (methanol, ethanol and propanol for L5, L6 and L7, respectively)) have been prepared and characterized by single-crystal X-ray diffraction (XRD), powder XRD, photoluminescence spectroscopy and thermogravimetric analysis. Complexes 1-5 are stair-step [Cu4I4] aggregate structures supported by two quinolyl-triazole hybrid ligands. Complexes 6 and 7 are rare cyclic [Cu3I3] aggregate-based 1-D coordination polymers. All ligands adopt a common tridentate-bridging coordination mode. These complexes are strongly luminescent with a yellow emission (500-700 nm) in the solid state. This journal is | - |
dc.language | eng | - |
dc.relation.ispartof | Dalton Transactions | - |
dc.title | Luminescent [Cu4I4] aggregates and [Cu3I3]-cyclic coordination polymers supported by quinolyl-triazoles | - |
dc.type | Article | - |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1039/c4dt03648d | - |
dc.identifier.scopus | eid_2-s2.0-84925310597 | - |
dc.identifier.hkuros | 285716 | - |
dc.identifier.volume | 44 | - |
dc.identifier.issue | 13 | - |
dc.identifier.spage | 6075 | - |
dc.identifier.epage | 6081 | - |
dc.identifier.eissn | 1477-9234 | - |
dc.identifier.isi | WOS:000351476600019 | - |
dc.identifier.issnl | 1477-9226 | - |