File Download

There are no files associated with this item.

  Links for fulltext
     (May Require Subscription)
Supplementary

Article: Synthesis and characterisation of adducts of [Pt2(μ-S)2(PPh3)4] with organo-palladium and platinum-hydride substrates

TitleSynthesis and characterisation of adducts of [Pt2(μ-S)2(PPh3)4] with organo-palladium and platinum-hydride substrates
Authors
KeywordsElectrospray mass spectrometry
Crystal structure
Platinum complexes
Sulfido ligands
Trinuclear complexes
Palladium complexes
Issue Date2010
Citation
Inorganica Chimica Acta, 2010, v. 363, n. 11, p. 2387-2393 How to Cite?
AbstractThe reactions of [Pt2(μ-S)2(PPh3) 4] towards a range of palladium(II) complexes containing organometallic ligands (cyclopalladated N-donor ligands, η3- allyl, phenyl) have been explored, leading to the formation of a series of cationic, trinuclear sulfido-bridged aggregates containing {Pt 2PdS2} cores. [Pt2(μ-S)2(PPh 3)4] also reacts with the platinum(II) hydride complex trans-[PtHCl(PPh3)2] giving the adduct [Pt 2(μ-S)2(PPh3)4PtH(PPh 3)]+. X-ray crystal structure determinations on the complexes [Pt2(μ-S)2(PPh3) 4PdPh(PPh3)]PF6 and [Pt2(μ-S) 2(PPh3)4PtH(PPh3)]PF6 are reported, and show the expected bis μ3-sulfido aggregates with three square-planar metal centres. © 2010 Elsevier B.V. All rights reserved.
Persistent Identifierhttp://hdl.handle.net/10722/237592
ISSN
2015 Impact Factor: 1.918
2015 SCImago Journal Rankings: 0.584
ISI Accession Number ID

 

DC FieldValueLanguage
dc.contributor.authorWhite, Bradley C.-
dc.contributor.authorHarrison, Dylan-
dc.contributor.authorHenderson, William-
dc.contributor.authorNicholson, Brian K.-
dc.contributor.authorAndy Hor, T. S.-
dc.date.accessioned2017-01-16T06:10:01Z-
dc.date.available2017-01-16T06:10:01Z-
dc.date.issued2010-
dc.identifier.citationInorganica Chimica Acta, 2010, v. 363, n. 11, p. 2387-2393-
dc.identifier.issn0020-1693-
dc.identifier.urihttp://hdl.handle.net/10722/237592-
dc.description.abstractThe reactions of [Pt2(μ-S)2(PPh3) 4] towards a range of palladium(II) complexes containing organometallic ligands (cyclopalladated N-donor ligands, η3- allyl, phenyl) have been explored, leading to the formation of a series of cationic, trinuclear sulfido-bridged aggregates containing {Pt 2PdS2} cores. [Pt2(μ-S)2(PPh 3)4] also reacts with the platinum(II) hydride complex trans-[PtHCl(PPh3)2] giving the adduct [Pt 2(μ-S)2(PPh3)4PtH(PPh 3)]+. X-ray crystal structure determinations on the complexes [Pt2(μ-S)2(PPh3) 4PdPh(PPh3)]PF6 and [Pt2(μ-S) 2(PPh3)4PtH(PPh3)]PF6 are reported, and show the expected bis μ3-sulfido aggregates with three square-planar metal centres. © 2010 Elsevier B.V. All rights reserved.-
dc.languageeng-
dc.relation.ispartofInorganica Chimica Acta-
dc.subjectElectrospray mass spectrometry-
dc.subjectCrystal structure-
dc.subjectPlatinum complexes-
dc.subjectSulfido ligands-
dc.subjectTrinuclear complexes-
dc.subjectPalladium complexes-
dc.titleSynthesis and characterisation of adducts of [Pt2(μ-S)2(PPh3)4] with organo-palladium and platinum-hydride substrates-
dc.typeArticle-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.doi10.1016/j.ica.2010.03.068-
dc.identifier.scopuseid_2-s2.0-77955425968-
dc.identifier.volume363-
dc.identifier.issue11-
dc.identifier.spage2387-
dc.identifier.epage2393-
dc.identifier.isiWOS:000280237200004-

Export via OAI-PMH Interface in XML Formats


OR


Export to Other Non-XML Formats