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Article: Substituted metal carbonyls. Part 25: Unidentate, intramolecular, and intermolecular bridging modes of 1,1′-bis(diphenylphosphino)ferrocene in M3S2(CO)9 (M = Fe, Ru) cluster derivatives

TitleSubstituted metal carbonyls. Part 25: Unidentate, intramolecular, and intermolecular bridging modes of 1,1′-bis(diphenylphosphino)ferrocene in M<inf>3</inf>S<inf>2</inf>(CO)<inf>9</inf> (M = Fe, Ru) cluster derivatives
Authors
Issue Date1994
Citation
Journal of Cluster Science, 1994, v. 5, n. 2, p. 327-340 How to Cite?
AbstractCarbonyl exchange of Fe3(μ3-S)2(CO)9 wioth 1,1′-bis(diphenylphosphino)ferrocene (dppf) in refluxing THF gives a cluster ligand with a pendant phosphine moiety, Fe3(μ3-S)2(CO)8 (gn1-Ph2PlC5H4)Fe(C5H4)P4 MePh2)]1-, 4. Addition of 1 to AuCl(SMe2) gives ClAu(μ-dppf) Fe4(μ3-S)2(CO)8, 8 (45%). Spectroscopic evidence is also obtained for (OC)8 (μ3-S)2Fe3(μ-dppf) Os3(CO)11, 7 and PdCl2[(μ-dppf)Fe3(μ3-D)2(CO)8]2, 9, from 1 and Os3(CO)11(CH3CN) and PdCl2CN)2, respectively. Crystal data dor 3: space group P21/n, a = 10.891(3) Å, b = 19.939(3) Å, c = 20.443(2) Å, β 100.17(2)°. Z = 4, 3917 reflections, R = 0.049. © 1994 Plenum Publishing Corporation.
Persistent Identifierhttp://hdl.handle.net/10722/237541
ISSN
2015 Impact Factor: 1.664
2015 SCImago Journal Rankings: 0.416

 

DC FieldValueLanguage
dc.contributor.authorFang, Zhi Gang-
dc.contributor.authorWen, Yuh Sheng-
dc.contributor.authorWong, Raymond K L-
dc.contributor.authorNg, Siu Choon-
dc.contributor.authorLiu, Ling Kang-
dc.contributor.authorAndy Hor, T. S.-
dc.date.accessioned2017-01-16T06:09:35Z-
dc.date.available2017-01-16T06:09:35Z-
dc.date.issued1994-
dc.identifier.citationJournal of Cluster Science, 1994, v. 5, n. 2, p. 327-340-
dc.identifier.issn1040-7278-
dc.identifier.urihttp://hdl.handle.net/10722/237541-
dc.description.abstractCarbonyl exchange of Fe3(μ3-S)2(CO)9 wioth 1,1′-bis(diphenylphosphino)ferrocene (dppf) in refluxing THF gives a cluster ligand with a pendant phosphine moiety, Fe3(μ3-S)2(CO)8 (gn1-Ph2PlC5H4)Fe(C5H4)P4 MePh2)]1-, 4. Addition of 1 to AuCl(SMe2) gives ClAu(μ-dppf) Fe4(μ3-S)2(CO)8, 8 (45%). Spectroscopic evidence is also obtained for (OC)8 (μ3-S)2Fe3(μ-dppf) Os3(CO)11, 7 and PdCl2[(μ-dppf)Fe3(μ3-D)2(CO)8]2, 9, from 1 and Os3(CO)11(CH3CN) and PdCl2CN)2, respectively. Crystal data dor 3: space group P21/n, a = 10.891(3) Å, b = 19.939(3) Å, c = 20.443(2) Å, β 100.17(2)°. Z = 4, 3917 reflections, R = 0.049. © 1994 Plenum Publishing Corporation.-
dc.languageeng-
dc.relation.ispartofJournal of Cluster Science-
dc.titleSubstituted metal carbonyls. Part 25: Unidentate, intramolecular, and intermolecular bridging modes of 1,1′-bis(diphenylphosphino)ferrocene in M<inf>3</inf>S<inf>2</inf>(CO)<inf>9</inf> (M = Fe, Ru) cluster derivatives-
dc.typeArticle-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.doi10.1007/BF01170716-
dc.identifier.scopuseid_2-s2.0-0000593432-
dc.identifier.volume5-
dc.identifier.issue2-
dc.identifier.spage327-
dc.identifier.epage340-
dc.identifier.eissn1572-8862-

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