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Article: Structure and bonding of [(SIPr)AgX] (X = Cl, Br, i and OTf)

TitleStructure and bonding of [(SIPr)AgX] (X = Cl, Br, i and OTf)
Authors
Wong, Valerie H LWhite, Andrew J PHor, T. S AndyHii, King Kuok
Issue Date2015
Citation
Chemical Communications, 2015, v. 51, n. 100, p. 17752-17755 How to Cite?
DOI: http://dx.doi.org/10.1039/c5cc07977b
Abstract© 2015 The Royal Society of Chemistry.A series of iso-structural complexes [(SIPr)AgX] (X = Cl, Br, I, OTf; SIPr = 1,3-bis(2,6-diisopropylphenyl)imidazolidene) were synthesised, including the first example of a N-heterocyclic carbene silver(i) complex containing an O-bound triflate. Bond Energy Dissociation and Natural Orbitals for Chemical Valence bond analyses (BEDA & ETS-NOCV) revealing a significant NHC → M σ-back-donation, which influences the stability and sigma-donicity of these complexes.
Persistent Identifierhttp://hdl.handle.net/10722/237518
ISSN
1359-7345
2021 Impact Factor: 6.065
2020 SCImago Journal Rankings: 1.837
ISI Accession Number ID
WOS:000366664300026

 

DC FieldValueLanguage
dc.contributor.authorWong, Valerie H L-
dc.contributor.authorWhite, Andrew J P-
dc.contributor.authorHor, T. S Andy-
dc.contributor.authorHii, King Kuok-
dc.date.accessioned2017-01-16T06:09:23Z-
dc.date.available2017-01-16T06:09:23Z-
dc.date.issued2015-
dc.identifier.citationChemical Communications, 2015, v. 51, n. 100, p. 17752-17755-
dc.identifier.issn1359-7345-
dc.identifier.urihttp://hdl.handle.net/10722/237518-
dc.description.abstract© 2015 The Royal Society of Chemistry.A series of iso-structural complexes [(SIPr)AgX] (X = Cl, Br, I, OTf; SIPr = 1,3-bis(2,6-diisopropylphenyl)imidazolidene) were synthesised, including the first example of a N-heterocyclic carbene silver(i) complex containing an O-bound triflate. Bond Energy Dissociation and Natural Orbitals for Chemical Valence bond analyses (BEDA & ETS-NOCV) revealing a significant NHC → M σ-back-donation, which influences the stability and sigma-donicity of these complexes.-
dc.languageeng-
dc.relation.ispartofChemical Communications-
dc.rightsThis work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.-
dc.titleStructure and bonding of [(SIPr)AgX] (X = Cl, Br, i and OTf)-
dc.typeArticle-
dc.description.naturepublished_or_final_version-
dc.identifier.doi10.1039/c5cc07977b-
dc.identifier.scopuseid_2-s2.0-84949525719-
dc.identifier.hkuros285704-
dc.identifier.volume51-
dc.identifier.issue100-
dc.identifier.spage17752-
dc.identifier.epage17755-
dc.identifier.eissn1364-548X-
dc.identifier.isiWOS:000366664300026-
dc.identifier.issnl1359-7345-

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