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Article: Structure and bonding of [(SIPr)AgX] (X = Cl, Br, i and OTf)
Title | Structure and bonding of [(SIPr)AgX] (X = Cl, Br, i and OTf) |
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Authors | |
Issue Date | 2015 |
Citation | Chemical Communications, 2015, v. 51, n. 100, p. 17752-17755 How to Cite? |
Abstract | © 2015 The Royal Society of Chemistry.A series of iso-structural complexes [(SIPr)AgX] (X = Cl, Br, I, OTf; SIPr = 1,3-bis(2,6-diisopropylphenyl)imidazolidene) were synthesised, including the first example of a N-heterocyclic carbene silver(i) complex containing an O-bound triflate. Bond Energy Dissociation and Natural Orbitals for Chemical Valence bond analyses (BEDA & ETS-NOCV) revealing a significant NHC → M σ-back-donation, which influences the stability and sigma-donicity of these complexes. |
Persistent Identifier | http://hdl.handle.net/10722/237518 |
ISSN | 2023 Impact Factor: 4.3 2023 SCImago Journal Rankings: 1.133 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Wong, Valerie H L | - |
dc.contributor.author | White, Andrew J P | - |
dc.contributor.author | Hor, T. S Andy | - |
dc.contributor.author | Hii, King Kuok | - |
dc.date.accessioned | 2017-01-16T06:09:23Z | - |
dc.date.available | 2017-01-16T06:09:23Z | - |
dc.date.issued | 2015 | - |
dc.identifier.citation | Chemical Communications, 2015, v. 51, n. 100, p. 17752-17755 | - |
dc.identifier.issn | 1359-7345 | - |
dc.identifier.uri | http://hdl.handle.net/10722/237518 | - |
dc.description.abstract | © 2015 The Royal Society of Chemistry.A series of iso-structural complexes [(SIPr)AgX] (X = Cl, Br, I, OTf; SIPr = 1,3-bis(2,6-diisopropylphenyl)imidazolidene) were synthesised, including the first example of a N-heterocyclic carbene silver(i) complex containing an O-bound triflate. Bond Energy Dissociation and Natural Orbitals for Chemical Valence bond analyses (BEDA & ETS-NOCV) revealing a significant NHC → M σ-back-donation, which influences the stability and sigma-donicity of these complexes. | - |
dc.language | eng | - |
dc.relation.ispartof | Chemical Communications | - |
dc.rights | This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License. | - |
dc.title | Structure and bonding of [(SIPr)AgX] (X = Cl, Br, i and OTf) | - |
dc.type | Article | - |
dc.description.nature | published_or_final_version | - |
dc.identifier.doi | 10.1039/c5cc07977b | - |
dc.identifier.scopus | eid_2-s2.0-84949525719 | - |
dc.identifier.hkuros | 285704 | - |
dc.identifier.volume | 51 | - |
dc.identifier.issue | 100 | - |
dc.identifier.spage | 17752 | - |
dc.identifier.epage | 17755 | - |
dc.identifier.eissn | 1364-548X | - |
dc.identifier.isi | WOS:000366664300026 | - |
dc.identifier.issnl | 1359-7345 | - |