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Article: Shell cross-linked micelle-based nanoreactors for the substrate-selective hydrolytic kinetic resolution of epoxides

TitleShell cross-linked micelle-based nanoreactors for the substrate-selective hydrolytic kinetic resolution of epoxides
Authors
Issue Date2011
PublisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/journals/jacsat/index.html
Citation
Journal of the American Chemical Society, 2011, v. 133 n. 36, p. 14260-14263 How to Cite?
AbstractShell cross-linked micelles (SCMs) containing Co(III)-salen cores were prepared from amphiphilic poly(2-oxazoline) triblock copolymers. The catalytic activity of these nanoreactors for the hydrolytic kinetic resolution of various terminal epoxides was investigated. The SCM catalysts showed high catalytic efficiency and, more significantly, substrate selectivity based on the hydrophobic nature of the epoxide. Moreover, because of the nanoscale particle size and the high stability, the catalyst could be recovered easily by ultrafiltration and reused with high activity for eight cycles.
Persistent Identifierhttp://hdl.handle.net/10722/231079
ISSN
2015 Impact Factor: 13.038
2015 SCImago Journal Rankings: 7.123

 

DC FieldValueLanguage
dc.contributor.authorLiu, Y-
dc.contributor.authorWang, Y-
dc.contributor.authorWang, Y-
dc.contributor.authorLu, J-
dc.contributor.authorPiñón, V-
dc.contributor.authorWeck, M-
dc.date.accessioned2016-09-02T02:23:04Z-
dc.date.available2016-09-02T02:23:04Z-
dc.date.issued2011-
dc.identifier.citationJournal of the American Chemical Society, 2011, v. 133 n. 36, p. 14260-14263-
dc.identifier.issn0002-7863-
dc.identifier.urihttp://hdl.handle.net/10722/231079-
dc.description.abstractShell cross-linked micelles (SCMs) containing Co(III)-salen cores were prepared from amphiphilic poly(2-oxazoline) triblock copolymers. The catalytic activity of these nanoreactors for the hydrolytic kinetic resolution of various terminal epoxides was investigated. The SCM catalysts showed high catalytic efficiency and, more significantly, substrate selectivity based on the hydrophobic nature of the epoxide. Moreover, because of the nanoscale particle size and the high stability, the catalyst could be recovered easily by ultrafiltration and reused with high activity for eight cycles.-
dc.languageeng-
dc.publisherAmerican Chemical Society. The Journal's web site is located at http://pubs.acs.org/journals/jacsat/index.html-
dc.relation.ispartofJournal of the American Chemical Society-
dc.titleShell cross-linked micelle-based nanoreactors for the substrate-selective hydrolytic kinetic resolution of epoxides-
dc.typeArticle-
dc.identifier.emailWang, Y: wanglab@hku.hk-
dc.identifier.authorityWang, Y=rp02191-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1021/ja206644d-
dc.identifier.scopuseid_2-s2.0-80052602350-
dc.identifier.volume133-
dc.identifier.issue36-
dc.identifier.spage14260-
dc.identifier.epage14263-
dc.publisher.placeUnited States-

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