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Article: M8L12 cubic cages with all facial Δ or facial Λ configuration: effects of surface anions on the occupancy of the cage and anion exchange

TitleM8L12 cubic cages with all facial Δ or facial Λ configuration: effects of surface anions on the occupancy of the cage and anion exchange
Authors
Issue Date2016
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.asp
Citation
Chemical Communications, 2016, v. 52 n. 35, p. 5981-5984 How to Cite?
AbstractM8L12 cubic cages (M = MnII, ZnII or CdII), with all eight metal ions having all facial [capital Delta] or facial [capital Lambda] configurations and having an encapsulated anion, were prepared by the self-assembly of m-xylene-bridged imidazolyl-imine ligands and MX2 (X = PF6-, SbF6-, TfO-) salts; the encapsulated anion exchange with different anions (SbF6-, Tf2N-, NO3-, TsO-) was studied and the results with NO3- and TsO- indicate that anions on the cage surfaces affect the encapsulated anion exchange and the occupancy of the cage.
Persistent Identifierhttp://hdl.handle.net/10722/229119
ISSN
2015 Impact Factor: 6.567
2015 SCImago Journal Rankings: 2.771

 

DC FieldValueLanguage
dc.contributor.authorYang, J-
dc.contributor.authorChang, X-
dc.contributor.authorSham, K-
dc.contributor.authorYiu, S-
dc.contributor.authorKwong, H-
dc.contributor.authorChe, CM-
dc.date.accessioned2016-08-23T14:09:07Z-
dc.date.available2016-08-23T14:09:07Z-
dc.date.issued2016-
dc.identifier.citationChemical Communications, 2016, v. 52 n. 35, p. 5981-5984-
dc.identifier.issn1359-7345-
dc.identifier.urihttp://hdl.handle.net/10722/229119-
dc.description.abstractM8L12 cubic cages (M = MnII, ZnII or CdII), with all eight metal ions having all facial [capital Delta] or facial [capital Lambda] configurations and having an encapsulated anion, were prepared by the self-assembly of m-xylene-bridged imidazolyl-imine ligands and MX2 (X = PF6-, SbF6-, TfO-) salts; the encapsulated anion exchange with different anions (SbF6-, Tf2N-, NO3-, TsO-) was studied and the results with NO3- and TsO- indicate that anions on the cage surfaces affect the encapsulated anion exchange and the occupancy of the cage.-
dc.languageeng-
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.asp-
dc.relation.ispartofChemical Communications-
dc.titleM8L12 cubic cages with all facial Δ or facial Λ configuration: effects of surface anions on the occupancy of the cage and anion exchange-
dc.typeArticle-
dc.identifier.emailChang, X: xychang@hku.hk-
dc.identifier.emailChe, CM: chemhead@hku.hk-
dc.identifier.authorityChe, CM=rp00670-
dc.identifier.doi10.1039/C6CC01635A-
dc.identifier.pmid27064122 -
dc.identifier.hkuros259922-
dc.identifier.volume52-
dc.identifier.issue35-
dc.identifier.spage5981-
dc.identifier.epage5984-
dc.publisher.placeUnited Kingdom-

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