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Article: M8L12 cubic cages with all facial Δ or facial Λ configuration: effects of surface anions on the occupancy of the cage and anion exchange

TitleM8L12 cubic cages with all facial Δ or facial Λ configuration: effects of surface anions on the occupancy of the cage and anion exchange
Authors
Yang, JChang, XSham, KYiu, SKwong, HChe, CM
Issue Date2016
PublisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.asp
Citation
Chemical Communications, 2016, v. 52 n. 35, p. 5981-5984 How to Cite?
DOI: http://dx.doi.org/10.1039/C6CC01635A
AbstractM8L12 cubic cages (M = MnII, ZnII or CdII), with all eight metal ions having all facial [capital Delta] or facial [capital Lambda] configurations and having an encapsulated anion, were prepared by the self-assembly of m-xylene-bridged imidazolyl-imine ligands and MX2 (X = PF6-, SbF6-, TfO-) salts; the encapsulated anion exchange with different anions (SbF6-, Tf2N-, NO3-, TsO-) was studied and the results with NO3- and TsO- indicate that anions on the cage surfaces affect the encapsulated anion exchange and the occupancy of the cage.
Persistent Identifierhttp://hdl.handle.net/10722/229119
ISSN
1359-7345
2021 Impact Factor: 6.065
2020 SCImago Journal Rankings: 1.837
ISI Accession Number ID
WOS:000374785800020

 

DC FieldValueLanguage
dc.contributor.authorYang, J-
dc.contributor.authorChang, X-
dc.contributor.authorSham, K-
dc.contributor.authorYiu, S-
dc.contributor.authorKwong, H-
dc.contributor.authorChe, CM-
dc.date.accessioned2016-08-23T14:09:07Z-
dc.date.available2016-08-23T14:09:07Z-
dc.date.issued2016-
dc.identifier.citationChemical Communications, 2016, v. 52 n. 35, p. 5981-5984-
dc.identifier.issn1359-7345-
dc.identifier.urihttp://hdl.handle.net/10722/229119-
dc.description.abstractM8L12 cubic cages (M = MnII, ZnII or CdII), with all eight metal ions having all facial [capital Delta] or facial [capital Lambda] configurations and having an encapsulated anion, were prepared by the self-assembly of m-xylene-bridged imidazolyl-imine ligands and MX2 (X = PF6-, SbF6-, TfO-) salts; the encapsulated anion exchange with different anions (SbF6-, Tf2N-, NO3-, TsO-) was studied and the results with NO3- and TsO- indicate that anions on the cage surfaces affect the encapsulated anion exchange and the occupancy of the cage.-
dc.languageeng-
dc.publisherRoyal Society of Chemistry. The Journal's web site is located at http://www.rsc.org/Publishing/Journals/cc/index.asp-
dc.relation.ispartofChemical Communications-
dc.titleM8L12 cubic cages with all facial Δ or facial Λ configuration: effects of surface anions on the occupancy of the cage and anion exchange-
dc.typeArticle-
dc.identifier.emailChang, X: xychang@hku.hk-
dc.identifier.emailChe, CM: chemhead@hku.hk-
dc.identifier.authorityChe, CM=rp00670-
dc.identifier.doi10.1039/C6CC01635A-
dc.identifier.pmid27064122-
dc.identifier.scopuseid_2-s2.0-84966783418-
dc.identifier.hkuros259922-
dc.identifier.volume52-
dc.identifier.issue35-
dc.identifier.spage5981-
dc.identifier.epage5984-
dc.identifier.isiWOS:000374785800020-
dc.publisher.placeUnited Kingdom-
dc.identifier.issnl1359-7345-

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