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Article: Peripheral cyanohexyl substituent in wide bandgap polymer: Increase the electron injection property for blue phosphorescence light emitting device

TitlePeripheral cyanohexyl substituent in wide bandgap polymer: Increase the electron injection property for blue phosphorescence light emitting device
Authors
Keywordshost
phorphosrescence
polymer
cyano group
wide bandgap
Issue Date2011
Citation
Macromolecular Rapid Communications, 2011, v. 32, n. 18, p. 1467-1471 How to Cite?
AbstractNovel blue phosphor host, PCNCzSi, using 3,6-linked carbazole with δ-π tetraphenylsilane segment as the main chain modified by peripheral cyanohexyl group was designed. The Si-carbazole backbone entitles the polymer with wide bandgap, high E T and good hole transporting ability. The introduction of peripheral CN group with high electron affinity enhances the electron injecting property of the polymer revealed by electron-only device and UPS measurement. Highly efficient spin-coated phosphorescent polymer light-emitting device, using PCNCzSi as the host for blue iridium complex, FIrpic, was realized. The maximum luminous efficiency and maximum external quantum efficiency of the device were 15 cd/A and 6.7%, respectively, which are very high values for blue phosphorescent device using polymers as hosts as known. Cyano group, which possesses strong electron-withdrawing property, was attached on the hexyl side chain to obtain wide band gap polymer, PCNCzSi. Highly efficient spin-coated phosphorescent polymer light-emitting device, using PCNCzSi as the host for blue iridium complex FIrpic was prepared, and the maximum luminous efficiency and maximum external quantum efficiency of the devices were reached to 15 cd/A and 6.7%, respectively. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Persistent Identifierhttp://hdl.handle.net/10722/225890
ISSN
2015 Impact Factor: 4.638
2015 SCImago Journal Rankings: 1.869

 

DC FieldValueLanguage
dc.contributor.authorHu, Dehua-
dc.contributor.authorCheng, Gang-
dc.contributor.authorLu, Ping-
dc.contributor.authorLiu, He-
dc.contributor.authorShen, Fangzhong-
dc.contributor.authorLi, Fenghong-
dc.contributor.authorLv, Ying-
dc.contributor.authorDong, Wenyue-
dc.contributor.authorMa, Yuguang-
dc.date.accessioned2016-05-23T02:22:05Z-
dc.date.available2016-05-23T02:22:05Z-
dc.date.issued2011-
dc.identifier.citationMacromolecular Rapid Communications, 2011, v. 32, n. 18, p. 1467-1471-
dc.identifier.issn1022-1336-
dc.identifier.urihttp://hdl.handle.net/10722/225890-
dc.description.abstractNovel blue phosphor host, PCNCzSi, using 3,6-linked carbazole with δ-π tetraphenylsilane segment as the main chain modified by peripheral cyanohexyl group was designed. The Si-carbazole backbone entitles the polymer with wide bandgap, high E T and good hole transporting ability. The introduction of peripheral CN group with high electron affinity enhances the electron injecting property of the polymer revealed by electron-only device and UPS measurement. Highly efficient spin-coated phosphorescent polymer light-emitting device, using PCNCzSi as the host for blue iridium complex, FIrpic, was realized. The maximum luminous efficiency and maximum external quantum efficiency of the device were 15 cd/A and 6.7%, respectively, which are very high values for blue phosphorescent device using polymers as hosts as known. Cyano group, which possesses strong electron-withdrawing property, was attached on the hexyl side chain to obtain wide band gap polymer, PCNCzSi. Highly efficient spin-coated phosphorescent polymer light-emitting device, using PCNCzSi as the host for blue iridium complex FIrpic was prepared, and the maximum luminous efficiency and maximum external quantum efficiency of the devices were reached to 15 cd/A and 6.7%, respectively. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.-
dc.languageeng-
dc.relation.ispartofMacromolecular Rapid Communications-
dc.subjecthost-
dc.subjectphorphosrescence-
dc.subjectpolymer-
dc.subjectcyano group-
dc.subjectwide bandgap-
dc.titlePeripheral cyanohexyl substituent in wide bandgap polymer: Increase the electron injection property for blue phosphorescence light emitting device-
dc.typeArticle-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.doi10.1002/marc.201100179-
dc.identifier.pmid21732464-
dc.identifier.scopuseid_2-s2.0-80052520747-
dc.identifier.volume32-
dc.identifier.issue18-
dc.identifier.spage1467-
dc.identifier.epage1471-
dc.identifier.eissn1521-3927-

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