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Article: 5-Substituted 1,3,4-oxathiazol-2-ones as a sulfur source for a sulfido cluster: Synthesis and molecular structure of the 48-electron equilateral triangular cluster anion [Mn3(μ3-S)2(CO)9]-

Title5-Substituted 1,3,4-oxathiazol-2-ones as a sulfur source for a sulfido cluster: Synthesis and molecular structure of the 48-electron equilateral triangular cluster anion [Mn3(μ3-S)2(CO)9]-
Authors
Issue Date1993
Citation
Organometallics, 1993, v. 12, n. 4, p. 1009-1011 How to Cite?
Abstract[Mn3(CO)9(μ3-S)2] - has been isolated from the reaction between [Mn(CO)5]- and 5-substituted 1,3,4-oxathiazol-2-one (RCNSCO(O); R = phenyl, methyl, 3,5-dinitrophenyl) in THF. X-ray analysis revealed a D3h equilateral triangular cluster with three Mn(CO)3 units (Mn-Mn = 2.7680(16)-2.7918(13) Å) apically bicapped by two μ3-S ligands. The use of 1,3,4-oxathiazol-2-ones as a sulfur precursor allows facile nucleophilic attack from the carbonylmetalate and subsequent elimination of RCN and CO2. © 1993 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/219838
ISSN
2015 Impact Factor: 4.186
2015 SCImago Journal Rankings: 2.043

 

DC FieldValueLanguage
dc.contributor.authorFang, Zhi Gang-
dc.contributor.authorHor, T. S Andy-
dc.contributor.authorMok, K. F.-
dc.contributor.authorNg, Siu Choon-
dc.contributor.authorLiu, Ling Kang-
dc.contributor.authorWen, Yuh Sheng-
dc.date.accessioned2015-09-23T02:58:04Z-
dc.date.available2015-09-23T02:58:04Z-
dc.date.issued1993-
dc.identifier.citationOrganometallics, 1993, v. 12, n. 4, p. 1009-1011-
dc.identifier.issn0276-7333-
dc.identifier.urihttp://hdl.handle.net/10722/219838-
dc.description.abstract[Mn3(CO)9(μ3-S)2] - has been isolated from the reaction between [Mn(CO)5]- and 5-substituted 1,3,4-oxathiazol-2-one (RCNSCO(O); R = phenyl, methyl, 3,5-dinitrophenyl) in THF. X-ray analysis revealed a D3h equilateral triangular cluster with three Mn(CO)3 units (Mn-Mn = 2.7680(16)-2.7918(13) Å) apically bicapped by two μ3-S ligands. The use of 1,3,4-oxathiazol-2-ones as a sulfur precursor allows facile nucleophilic attack from the carbonylmetalate and subsequent elimination of RCN and CO2. © 1993 American Chemical Society.-
dc.languageeng-
dc.relation.ispartofOrganometallics-
dc.title5-Substituted 1,3,4-oxathiazol-2-ones as a sulfur source for a sulfido cluster: Synthesis and molecular structure of the 48-electron equilateral triangular cluster anion [Mn3(μ3-S)2(CO)9]--
dc.typeArticle-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.scopuseid_2-s2.0-0000892745-
dc.identifier.volume12-
dc.identifier.issue4-
dc.identifier.spage1009-
dc.identifier.epage1011-

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