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Article: Chloride substitution of [CpRu(dppf)Cl] with sulfur-containing ligands

TitleChloride substitution of [CpRu(dppf)Cl] with sulfur-containing ligands
Authors
KeywordsRuthenium
1,1′-Bis(diphenylphosphino)ferrocene
Crystal structures
Cyclopentadienyl
Sulfur-containing ligands
Issue Date2004
Citation
Journal of Organometallic Chemistry, 2004, v. 689, n. 9, p. 1444-1451 How to Cite?
AbstractThe reactions of CpRu(dppf)Cl (1) with the sulfur-containing ligands, thiophenol HSPh, 2-mercaptopyridine C5H4N(SH), thiourea SC(NH2)2, vinylene trithiocarbonate SCS(CH)2S and ethylene trithiocarbonate SCS(CH2)2S, yielded chloro-substituted derivatives, viz. the mono-ruthenium(II) complexes CpRu(dppf)(SPh) (2), [CpRu(dppf)(SC5H4NH)]BPh4 (3)BPh4, [CpRu(dppf)(SC(NH2)2] PF6 (4)PF6, [CpRu(dppf)(SCS(CH)2S)]Cl (5)Cl and [CpRu(dppf)(SCS(CH2)2S)]Cl (6)Cl, respectively. Treatment of 1 with AuCl(SMe2) in the presence of NH4PF6 gave [(CpRu(dppf)(SMe2)] PF6 (7)PF6. The reaction of 1 or 6 with SnCl2 resulted in cleavage of chloro and dithiocarbonate ligands, respectively, to give CpRu(dppf)SnCl3 (8). All complexes were spectroscopically characterized and the structures of 2 and cationic complexes 4-7 were determined by single-crystal diffraction analyses. © 2004 Elsevier B.V. All rights reserved.
Persistent Identifierhttp://hdl.handle.net/10722/219819
ISSN
2015 Impact Factor: 2.336
2015 SCImago Journal Rankings: 0.732

 

DC FieldValueLanguage
dc.contributor.authorLu, Xiu Lian-
dc.contributor.authorVittal, Jagadese J.-
dc.contributor.authorTiekink, Edward R T-
dc.contributor.authorGoh, Lai Yoong-
dc.contributor.authorHor, T. S Andy-
dc.date.accessioned2015-09-23T02:58:01Z-
dc.date.available2015-09-23T02:58:01Z-
dc.date.issued2004-
dc.identifier.citationJournal of Organometallic Chemistry, 2004, v. 689, n. 9, p. 1444-1451-
dc.identifier.issn0022-328X-
dc.identifier.urihttp://hdl.handle.net/10722/219819-
dc.description.abstractThe reactions of CpRu(dppf)Cl (1) with the sulfur-containing ligands, thiophenol HSPh, 2-mercaptopyridine C5H4N(SH), thiourea SC(NH2)2, vinylene trithiocarbonate SCS(CH)2S and ethylene trithiocarbonate SCS(CH2)2S, yielded chloro-substituted derivatives, viz. the mono-ruthenium(II) complexes CpRu(dppf)(SPh) (2), [CpRu(dppf)(SC5H4NH)]BPh4 (3)BPh4, [CpRu(dppf)(SC(NH2)2] PF6 (4)PF6, [CpRu(dppf)(SCS(CH)2S)]Cl (5)Cl and [CpRu(dppf)(SCS(CH2)2S)]Cl (6)Cl, respectively. Treatment of 1 with AuCl(SMe2) in the presence of NH4PF6 gave [(CpRu(dppf)(SMe2)] PF6 (7)PF6. The reaction of 1 or 6 with SnCl2 resulted in cleavage of chloro and dithiocarbonate ligands, respectively, to give CpRu(dppf)SnCl3 (8). All complexes were spectroscopically characterized and the structures of 2 and cationic complexes 4-7 were determined by single-crystal diffraction analyses. © 2004 Elsevier B.V. All rights reserved.-
dc.languageeng-
dc.relation.ispartofJournal of Organometallic Chemistry-
dc.subjectRuthenium-
dc.subject1,1′-Bis(diphenylphosphino)ferrocene-
dc.subjectCrystal structures-
dc.subjectCyclopentadienyl-
dc.subjectSulfur-containing ligands-
dc.titleChloride substitution of [CpRu(dppf)Cl] with sulfur-containing ligands-
dc.typeArticle-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.doi10.1016/j.jorganchem.2003.12.020-
dc.identifier.scopuseid_2-s2.0-1842716756-
dc.identifier.volume689-
dc.identifier.issue9-
dc.identifier.spage1444-
dc.identifier.epage1451-

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