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Article: Substituted metal carbonyls. I. Molybdenum carbonyl complexes containing unidentate and bridging diphosphines: One-pot syntheses

TitleSubstituted metal carbonyls. I. Molybdenum carbonyl complexes containing unidentate and bridging diphosphines: One-pot syntheses
Authors
Issue Date1987
Citation
Journal of Organometallic Chemistry, 1987, v. 319, n. 2, p. 213-217 How to Cite?
AbstractTrimethylamine N-oxide (TMNO)-initiated decarbonylations of Mo(CO)6 followed by phosphine additions yield the complexes Mo(CO)5(Ph2PCH2PPh2), which consists of a unidentate diphosphine, and the dinuclear phosphine-bridged complexes Mo2(CO)10(μ-Ph2P(CH2)nPPh2) (where n = 2, 3) at ambient temperatures. The IR and NMR (1H and 31P) spectroscopic and structural properties of these complexes are presented and discussed. Some thermal analytical data are summarised. © 1987.
Persistent Identifierhttp://hdl.handle.net/10722/219810
ISSN
2015 Impact Factor: 2.336
2015 SCImago Journal Rankings: 0.732

 

DC FieldValueLanguage
dc.contributor.authorHor, T. S Andy-
dc.date.accessioned2015-09-23T02:58:00Z-
dc.date.available2015-09-23T02:58:00Z-
dc.date.issued1987-
dc.identifier.citationJournal of Organometallic Chemistry, 1987, v. 319, n. 2, p. 213-217-
dc.identifier.issn0022-328X-
dc.identifier.urihttp://hdl.handle.net/10722/219810-
dc.description.abstractTrimethylamine N-oxide (TMNO)-initiated decarbonylations of Mo(CO)6 followed by phosphine additions yield the complexes Mo(CO)5(Ph2PCH2PPh2), which consists of a unidentate diphosphine, and the dinuclear phosphine-bridged complexes Mo2(CO)10(μ-Ph2P(CH2)nPPh2) (where n = 2, 3) at ambient temperatures. The IR and NMR (1H and 31P) spectroscopic and structural properties of these complexes are presented and discussed. Some thermal analytical data are summarised. © 1987.-
dc.languageeng-
dc.relation.ispartofJournal of Organometallic Chemistry-
dc.titleSubstituted metal carbonyls. I. Molybdenum carbonyl complexes containing unidentate and bridging diphosphines: One-pot syntheses-
dc.typeArticle-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.doi10.1016/0022-328X(87)83028-0-
dc.identifier.scopuseid_2-s2.0-0010850417-
dc.identifier.volume319-
dc.identifier.issue2-
dc.identifier.spage213-
dc.identifier.epage217-

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