File Download

There are no files associated with this item.

  Links for fulltext
     (May Require Subscription)
Supplementary

Article: Metal-Organic Frameworks via Emissive Metal-Carboxylate Zwitterion Intermediates

TitleMetal-Organic Frameworks via Emissive Metal-Carboxylate Zwitterion Intermediates
Authors
Keywordsmetal-organic frameworks
metal-carboxylate zwitterions
photoluminescence
Issue Date2015
Citation
ChemPlusChem, 2015, v. 80, n. 8, p. 1231-1234 How to Cite?
Abstract© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. Pyridinemethanol-carboxylate esters form octahedral complexes with Zn(NO3)2 in aqueous DMF that subsequently undergo hydrolysis at elevated temperatures to form metal-carboxylate zwitterions. In situ deprotonation of the hydroxy group leads to thermally robust, neutral MOFs. This stepwise synthesis can be controlled by temperature and is made possible by the subtle difference in reactivity of the functional groups. Emissive intermediates: Pyridinemethanol-carboxylate esters form octahedral complexes with Zn(NO3)2 in aqueous DMF that subsequently undergo hydrolysis at elevated temperatures to form emissive metal-carboxylate zwitterions (see picture). In situ deprotonation of the hydroxy group leads to thermally robust, neutral MOFs.
Persistent Identifierhttp://hdl.handle.net/10722/219800

 

DC FieldValueLanguage
dc.contributor.authorArmaghan, Mahsa-
dc.contributor.authorShang, Xiu Juan-
dc.contributor.authorYuan, Yan Qiu-
dc.contributor.authorYoung, David J.-
dc.contributor.authorZhang, Wen Hua-
dc.contributor.authorHor, T. S Andy-
dc.contributor.authorLang, Jian Ping-
dc.date.accessioned2015-09-23T02:57:59Z-
dc.date.available2015-09-23T02:57:59Z-
dc.date.issued2015-
dc.identifier.citationChemPlusChem, 2015, v. 80, n. 8, p. 1231-1234-
dc.identifier.urihttp://hdl.handle.net/10722/219800-
dc.description.abstract© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. Pyridinemethanol-carboxylate esters form octahedral complexes with Zn(NO<inf>3</inf>)<inf>2</inf> in aqueous DMF that subsequently undergo hydrolysis at elevated temperatures to form metal-carboxylate zwitterions. In situ deprotonation of the hydroxy group leads to thermally robust, neutral MOFs. This stepwise synthesis can be controlled by temperature and is made possible by the subtle difference in reactivity of the functional groups. Emissive intermediates: Pyridinemethanol-carboxylate esters form octahedral complexes with Zn(NO<inf>3</inf>)<inf>2</inf> in aqueous DMF that subsequently undergo hydrolysis at elevated temperatures to form emissive metal-carboxylate zwitterions (see picture). In situ deprotonation of the hydroxy group leads to thermally robust, neutral MOFs.-
dc.languageeng-
dc.relation.ispartofChemPlusChem-
dc.subjectmetal-organic frameworks-
dc.subjectmetal-carboxylate zwitterions-
dc.subjectphotoluminescence-
dc.titleMetal-Organic Frameworks via Emissive Metal-Carboxylate Zwitterion Intermediates-
dc.typeArticle-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.doi10.1002/cplu.201500134-
dc.identifier.scopuseid_2-s2.0-84938421485-
dc.identifier.volume80-
dc.identifier.issue8-
dc.identifier.spage1231-
dc.identifier.epage1234-
dc.identifier.eissn2192-6506-

Export via OAI-PMH Interface in XML Formats


OR


Export to Other Non-XML Formats