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Article: Isolation of first row transition metal-carboxylate zwitterions

TitleIsolation of first row transition metal-carboxylate zwitterions
Authors
Issue Date2015
Citation
RSC Advances, 2015, v. 5, n. 53, p. 42978-42989 How to Cite?
Abstract© The Royal Society of Chemistry 2015. Zwitterionic 3d metal carboxylates of Zn(ii), Cu(ii), Ni(ii) and Co(ii) have been isolated and structurally authenticated by X-ray crystallography. A series of 2-hydroxymethylpyridine-carboxylate ligands with different sizes and shapes demonstrate variable coordination modes with first row transition metals under different conditions, yielding a class of 17 complexes, predominantly zwitterions. The nature of the ligands permits the carboxylates to be un-coordinated, anionic and conjugated, thereby balancing the positive charges on the metal centers. This journal is
Persistent Identifierhttp://hdl.handle.net/10722/219787

 

DC FieldValueLanguage
dc.contributor.authorArmaghan, Mahsa-
dc.contributor.authorLu, W. Y James-
dc.contributor.authorWu, Di-
dc.contributor.authorWei, Yao-
dc.contributor.authorYuan, Feng Ling-
dc.contributor.authorNg, Seik Weng-
dc.contributor.authorAmini, Mostafa M.-
dc.contributor.authorZhang, Wen Hua-
dc.contributor.authorYoung, David J.-
dc.contributor.authorHor, T. S Andy-
dc.contributor.authorLang, Jian Ping-
dc.date.accessioned2015-09-23T02:57:57Z-
dc.date.available2015-09-23T02:57:57Z-
dc.date.issued2015-
dc.identifier.citationRSC Advances, 2015, v. 5, n. 53, p. 42978-42989-
dc.identifier.urihttp://hdl.handle.net/10722/219787-
dc.description.abstract© The Royal Society of Chemistry 2015. Zwitterionic 3d metal carboxylates of Zn(ii), Cu(ii), Ni(ii) and Co(ii) have been isolated and structurally authenticated by X-ray crystallography. A series of 2-hydroxymethylpyridine-carboxylate ligands with different sizes and shapes demonstrate variable coordination modes with first row transition metals under different conditions, yielding a class of 17 complexes, predominantly zwitterions. The nature of the ligands permits the carboxylates to be un-coordinated, anionic and conjugated, thereby balancing the positive charges on the metal centers. This journal is-
dc.languageeng-
dc.relation.ispartofRSC Advances-
dc.titleIsolation of first row transition metal-carboxylate zwitterions-
dc.typeArticle-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.doi10.1039/c5ra05564d-
dc.identifier.scopuseid_2-s2.0-84929377633-
dc.identifier.volume5-
dc.identifier.issue53-
dc.identifier.spage42978-
dc.identifier.epage42989-
dc.identifier.eissn2046-2069-

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