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- Publisher Website: 10.1039/c3dt52176a
- Scopus: eid_2-s2.0-84889684920
- PMID: 24131937
- WOS: WOS:000327665200025
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Article: Magnetocaloric effect of a series of remarkably isostructural intermetallic [NiII 3LnIII] cubane aggregates
Title | Magnetocaloric effect of a series of remarkably isostructural intermetallic [NiII 3LnIII] cubane aggregates |
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Authors | |
Issue Date | 2014 |
Citation | Dalton Transactions, 2014, v. 43, n. 1, p. 182-187 How to Cite? |
Abstract | A new series of remarkably isostructural 3d-4f compounds, [Ni 3Ln(hmp)4(OAc)5]·H2O· CH2Cl2 (Ln = Gd (1), Tb (2), Dy (3), Ho (4), Y (5)) were synthesized based on a simple one-pot self-assembly method. Magnetic measurements demonstrated the ferromagnetic property of the [Ni3Ln] cores and the heterometallic influence on the magnetocaloric properties. This study suggested that robust and discrete intermetallic cubanes can be an alternative to other magnetically active materials such as high-nuclearity aggregates or clusters whose structures are not generally controlled by common synthetic methodological designs. © 2014 The Royal Society of Chemistry. |
Persistent Identifier | http://hdl.handle.net/10722/219735 |
ISSN | 2023 Impact Factor: 3.5 2023 SCImago Journal Rankings: 0.697 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Wang, Pei | - |
dc.contributor.author | Shannigrahi, Santiranjan | - |
dc.contributor.author | Yakovlev, Nikolai L. | - |
dc.contributor.author | Hor, T. S Andy | - |
dc.date.accessioned | 2015-09-23T02:57:50Z | - |
dc.date.available | 2015-09-23T02:57:50Z | - |
dc.date.issued | 2014 | - |
dc.identifier.citation | Dalton Transactions, 2014, v. 43, n. 1, p. 182-187 | - |
dc.identifier.issn | 1477-9226 | - |
dc.identifier.uri | http://hdl.handle.net/10722/219735 | - |
dc.description.abstract | A new series of remarkably isostructural 3d-4f compounds, [Ni 3Ln(hmp)4(OAc)5]·H2O· CH2Cl2 (Ln = Gd (1), Tb (2), Dy (3), Ho (4), Y (5)) were synthesized based on a simple one-pot self-assembly method. Magnetic measurements demonstrated the ferromagnetic property of the [Ni3Ln] cores and the heterometallic influence on the magnetocaloric properties. This study suggested that robust and discrete intermetallic cubanes can be an alternative to other magnetically active materials such as high-nuclearity aggregates or clusters whose structures are not generally controlled by common synthetic methodological designs. © 2014 The Royal Society of Chemistry. | - |
dc.language | eng | - |
dc.relation.ispartof | Dalton Transactions | - |
dc.title | Magnetocaloric effect of a series of remarkably isostructural intermetallic [NiII 3LnIII] cubane aggregates | - |
dc.type | Article | - |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1039/c3dt52176a | - |
dc.identifier.pmid | 24131937 | - |
dc.identifier.scopus | eid_2-s2.0-84889684920 | - |
dc.identifier.volume | 43 | - |
dc.identifier.issue | 1 | - |
dc.identifier.spage | 182 | - |
dc.identifier.epage | 187 | - |
dc.identifier.eissn | 1477-9234 | - |
dc.identifier.isi | WOS:000327665200025 | - |
dc.identifier.issnl | 1477-9226 | - |