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Article: Magnetocaloric effect of a series of remarkably isostructural intermetallic [NiII 3LnIII] cubane aggregates

TitleMagnetocaloric effect of a series of remarkably isostructural intermetallic [NiII 3LnIII] cubane aggregates
Authors
Issue Date2014
Citation
Dalton Transactions, 2014, v. 43, n. 1, p. 182-187 How to Cite?
AbstractA new series of remarkably isostructural 3d-4f compounds, [Ni 3Ln(hmp)4(OAc)5]·H2O· CH2Cl2 (Ln = Gd (1), Tb (2), Dy (3), Ho (4), Y (5)) were synthesized based on a simple one-pot self-assembly method. Magnetic measurements demonstrated the ferromagnetic property of the [Ni3Ln] cores and the heterometallic influence on the magnetocaloric properties. This study suggested that robust and discrete intermetallic cubanes can be an alternative to other magnetically active materials such as high-nuclearity aggregates or clusters whose structures are not generally controlled by common synthetic methodological designs. © 2014 The Royal Society of Chemistry.
Persistent Identifierhttp://hdl.handle.net/10722/219735
ISSN
2015 Impact Factor: 4.177
2015 SCImago Journal Rankings: 1.404

 

DC FieldValueLanguage
dc.contributor.authorWang, Pei-
dc.contributor.authorShannigrahi, Santiranjan-
dc.contributor.authorYakovlev, Nikolai L.-
dc.contributor.authorHor, T. S Andy-
dc.date.accessioned2015-09-23T02:57:50Z-
dc.date.available2015-09-23T02:57:50Z-
dc.date.issued2014-
dc.identifier.citationDalton Transactions, 2014, v. 43, n. 1, p. 182-187-
dc.identifier.issn1477-9226-
dc.identifier.urihttp://hdl.handle.net/10722/219735-
dc.description.abstractA new series of remarkably isostructural 3d-4f compounds, [Ni 3Ln(hmp)4(OAc)5]·H2O· CH2Cl2 (Ln = Gd (1), Tb (2), Dy (3), Ho (4), Y (5)) were synthesized based on a simple one-pot self-assembly method. Magnetic measurements demonstrated the ferromagnetic property of the [Ni3Ln] cores and the heterometallic influence on the magnetocaloric properties. This study suggested that robust and discrete intermetallic cubanes can be an alternative to other magnetically active materials such as high-nuclearity aggregates or clusters whose structures are not generally controlled by common synthetic methodological designs. © 2014 The Royal Society of Chemistry.-
dc.languageeng-
dc.relation.ispartofDalton Transactions-
dc.titleMagnetocaloric effect of a series of remarkably isostructural intermetallic [NiII 3LnIII] cubane aggregates-
dc.typeArticle-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.doi10.1039/c3dt52176a-
dc.identifier.scopuseid_2-s2.0-84889684920-
dc.identifier.volume43-
dc.identifier.issue1-
dc.identifier.spage182-
dc.identifier.epage187-
dc.identifier.eissn1477-9234-

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