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Article: Facile self-assembly of intermetallic [Ni2Gd2] cubane aggregate for magnetic refrigeration

TitleFacile self-assembly of intermetallic [Ni2Gd2] cubane aggregate for magnetic refrigeration
Authors
Keywordsmetal aggregates
magnetocaloric effect
magnetic properties
intermetallic
heterometallic complexes
Issue Date2013
Citation
Chemistry - An Asian Journal, 2013, v. 8, n. 12, p. 2943-2946 How to Cite?
AbstractCubane Cooler: An intermetallic cubane aggregate shows a pronounced cryogenic magnetocaloric effect (MCE). A mixed-metal [Ni2Gd 2] cubane was assembled by the use of 2-(hydroxymethyl)pyridine (hmpH) as a spacer in a simple one-pot reaction. Its MCE measurement gives 34.4 J kg-1 K-1 at 4.5 K, suggesting that, apart from the commonly used large-nuclearity metal aggregates, smaller metal cubanes can also exhibit a large MCE. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Persistent Identifierhttp://hdl.handle.net/10722/219733
ISSN
2015 Impact Factor: 4.592
2015 SCImago Journal Rankings: 1.833

 

DC FieldValueLanguage
dc.contributor.authorWang, Pei-
dc.contributor.authorShannigrahi, Santiranjan-
dc.contributor.authorYakovlev, Nikolai L.-
dc.contributor.authorHor, T. S Andy-
dc.date.accessioned2015-09-23T02:57:50Z-
dc.date.available2015-09-23T02:57:50Z-
dc.date.issued2013-
dc.identifier.citationChemistry - An Asian Journal, 2013, v. 8, n. 12, p. 2943-2946-
dc.identifier.issn1861-4728-
dc.identifier.urihttp://hdl.handle.net/10722/219733-
dc.description.abstractCubane Cooler: An intermetallic cubane aggregate shows a pronounced cryogenic magnetocaloric effect (MCE). A mixed-metal [Ni2Gd 2] cubane was assembled by the use of 2-(hydroxymethyl)pyridine (hmpH) as a spacer in a simple one-pot reaction. Its MCE measurement gives 34.4 J kg-1 K-1 at 4.5 K, suggesting that, apart from the commonly used large-nuclearity metal aggregates, smaller metal cubanes can also exhibit a large MCE. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.-
dc.languageeng-
dc.relation.ispartofChemistry - An Asian Journal-
dc.subjectmetal aggregates-
dc.subjectmagnetocaloric effect-
dc.subjectmagnetic properties-
dc.subjectintermetallic-
dc.subjectheterometallic complexes-
dc.titleFacile self-assembly of intermetallic [Ni2Gd2] cubane aggregate for magnetic refrigeration-
dc.typeArticle-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.doi10.1002/asia.201300838-
dc.identifier.scopuseid_2-s2.0-84888341644-
dc.identifier.volume8-
dc.identifier.issue12-
dc.identifier.spage2943-
dc.identifier.epage2946-
dc.identifier.eissn1861-471X-

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