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Article: "click-and-click"-hybridised 1,2,3-triazoles supported Cu(i) coordination polymers for azide-alkyne cycloaddition

Title"click-and-click"-hybridised 1,2,3-triazoles supported Cu(i) coordination polymers for azide-alkyne cycloaddition
Authors
Issue Date2013
Citation
Dalton Transactions, 2013, v. 42, n. 26, p. 9437-9443 How to Cite?
AbstractTwo novel pyridyl and thioether hybridised 1,2,3-triazole ligands 1-(2-picolyl)-4-(2-(methylthio)-pyridine)-1H-1,2,3-triazole (L1) and 1-(4-picolyl)-4-(2-(methylthio)-pyridine)-1H-1,2,3-triazole (L2) were prepared from CuAAC click reactions. Reactions of CuI with the ligands L1 and L2 yielded two one-dimensional coordination polymers [Cu6I6(L1) 2]n (1) and [Cu2I2(L2) 2]n (2). Single-crystal X-ray diffraction reveals that 1 and 2 are polymeric with [Cu6I6] and [Cu2I 2] respectively as building blocks. Both ligands (L1 and L2) and complexes (1 and 2) are photoluminescence active. Complexes 1 and 2 are also catalytically active towards azide-alkyne cycloaddition reactions. This journal is © The Royal Society of Chemistry 2013.
Persistent Identifierhttp://hdl.handle.net/10722/219708
ISSN
2015 Impact Factor: 4.177
2015 SCImago Journal Rankings: 1.404

 

DC FieldValueLanguage
dc.contributor.authorJiang, Lu-
dc.contributor.authorWang, Zhe-
dc.contributor.authorBai, Shi Qiang-
dc.contributor.authorHor, T. S Andy-
dc.date.accessioned2015-09-23T02:57:46Z-
dc.date.available2015-09-23T02:57:46Z-
dc.date.issued2013-
dc.identifier.citationDalton Transactions, 2013, v. 42, n. 26, p. 9437-9443-
dc.identifier.issn1477-9226-
dc.identifier.urihttp://hdl.handle.net/10722/219708-
dc.description.abstractTwo novel pyridyl and thioether hybridised 1,2,3-triazole ligands 1-(2-picolyl)-4-(2-(methylthio)-pyridine)-1H-1,2,3-triazole (L1) and 1-(4-picolyl)-4-(2-(methylthio)-pyridine)-1H-1,2,3-triazole (L2) were prepared from CuAAC click reactions. Reactions of CuI with the ligands L1 and L2 yielded two one-dimensional coordination polymers [Cu6I6(L1) 2]n (1) and [Cu2I2(L2) 2]n (2). Single-crystal X-ray diffraction reveals that 1 and 2 are polymeric with [Cu6I6] and [Cu2I 2] respectively as building blocks. Both ligands (L1 and L2) and complexes (1 and 2) are photoluminescence active. Complexes 1 and 2 are also catalytically active towards azide-alkyne cycloaddition reactions. This journal is © The Royal Society of Chemistry 2013.-
dc.languageeng-
dc.relation.ispartofDalton Transactions-
dc.title"click-and-click"-hybridised 1,2,3-triazoles supported Cu(i) coordination polymers for azide-alkyne cycloaddition-
dc.typeArticle-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.doi10.1039/c3dt50987g-
dc.identifier.pmid23695801-
dc.identifier.scopuseid_2-s2.0-84880640924-
dc.identifier.volume42-
dc.identifier.issue26-
dc.identifier.spage9437-
dc.identifier.epage9443-
dc.identifier.eissn1477-9234-

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