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Article: Structural effects of sodium cations in polynuclear, multicubane-type mixed Na-Ni complexes

TitleStructural effects of sodium cations in polynuclear, multicubane-type mixed Na-Ni complexes
Authors
KeywordsPolynuclear complexes
Nickel
Metallacrown compounds
Magnetic properties
Clusters compounds
Issue Date2010
Citation
Angewandte Chemie - International Edition, 2010, v. 49, n. 26, p. 4443-4446 How to Cite?
Abstract(Figure Presented) Cubanes and beyond: Diversity and originality characterize the Ni complexes obtained from sodium (pyridine-2-yl)methanolate. The ligand/metal ratio and the presence of Na+ are key parameters to explain the formation of Ni4Na3, Ni6Na, or Ni7 polynuclear complexes with magnetically interacting centers. Such observations are relevant to the possible in situ formation of unexpected and possibly overlooked active species in catalytic reactions. © 2010 WIley-VCH Verlag GmbH & Co. KGaA, Weinheim.
Persistent Identifierhttp://hdl.handle.net/10722/219625
ISSN
2015 Impact Factor: 11.709
2015 SCImago Journal Rankings: 6.229

 

DC FieldValueLanguage
dc.contributor.authorZhang, Jun-
dc.contributor.authorTeo, Peili-
dc.contributor.authorPattacini, Roberto-
dc.contributor.authorKermagoret, Anthony-
dc.contributor.authorWelter, Richard-
dc.contributor.authorRogez, Guillaume-
dc.contributor.authorHor, T. S Andy-
dc.contributor.authorBraunstein, Pierre-
dc.date.accessioned2015-09-23T02:57:33Z-
dc.date.available2015-09-23T02:57:33Z-
dc.date.issued2010-
dc.identifier.citationAngewandte Chemie - International Edition, 2010, v. 49, n. 26, p. 4443-4446-
dc.identifier.issn1433-7851-
dc.identifier.urihttp://hdl.handle.net/10722/219625-
dc.description.abstract(Figure Presented) Cubanes and beyond: Diversity and originality characterize the Ni complexes obtained from sodium (pyridine-2-yl)methanolate. The ligand/metal ratio and the presence of Na+ are key parameters to explain the formation of Ni4Na3, Ni6Na, or Ni7 polynuclear complexes with magnetically interacting centers. Such observations are relevant to the possible in situ formation of unexpected and possibly overlooked active species in catalytic reactions. © 2010 WIley-VCH Verlag GmbH & Co. KGaA, Weinheim.-
dc.languageeng-
dc.relation.ispartofAngewandte Chemie - International Edition-
dc.subjectPolynuclear complexes-
dc.subjectNickel-
dc.subjectMetallacrown compounds-
dc.subjectMagnetic properties-
dc.subjectClusters compounds-
dc.titleStructural effects of sodium cations in polynuclear, multicubane-type mixed Na-Ni complexes-
dc.typeArticle-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.doi10.1002/anie.201001412-
dc.identifier.scopuseid_2-s2.0-77953664805-
dc.identifier.volume49-
dc.identifier.issue26-
dc.identifier.spage4443-
dc.identifier.epage4446-
dc.identifier.eissn1521-3773-

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