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Article: One-pot oxidation and protonation of a bridging sulfide and rare crystallographic evidence of a coordinated [SO] complex in [Pt 2(μ-S2O2H)(PPh3) 4]+

TitleOne-pot oxidation and protonation of a bridging sulfide and rare crystallographic evidence of a coordinated [SO] complex in [Pt 2(μ-S2O2H)(PPh3) 4]+
Authors
Li, JingqiuKoh, Lip LinHor, T. S Andy
Issue Date2009
Citation
Chemical Communications, 2009, n. 23, p. 3416-3418 How to Cite?
DOI: http://dx.doi.org/10.1039/b902625h
AbstractOne-pot oxidation and protonation of the sulfide bridging complex [Pt 2(μ-S)2(PPh3)4] can be promoted by lanthanide or scandium compounds, leading to the isolation of [Pt 2(μ-S2O2H)(PPh3) 4]+; crystallographic elucidation confirmed sulfide mono-oxygenation without S-S bonding to give formally [SO]2- in the form of an [SOHOS]3- overhead bridge. © 2009 The Royal Society of Chemistry.
Persistent Identifierhttp://hdl.handle.net/10722/219601
ISSN
1359-7345
2023 Impact Factor: 4.3
2023 SCImago Journal Rankings: 1.133
ISI Accession Number ID
WOS:000266674700028

 

DC FieldValueLanguage
dc.contributor.authorLi, Jingqiu-
dc.contributor.authorKoh, Lip Lin-
dc.contributor.authorHor, T. S Andy-
dc.date.accessioned2015-09-23T02:57:30Z-
dc.date.available2015-09-23T02:57:30Z-
dc.date.issued2009-
dc.identifier.citationChemical Communications, 2009, n. 23, p. 3416-3418-
dc.identifier.issn1359-7345-
dc.identifier.urihttp://hdl.handle.net/10722/219601-
dc.description.abstractOne-pot oxidation and protonation of the sulfide bridging complex [Pt 2(μ-S)2(PPh3)4] can be promoted by lanthanide or scandium compounds, leading to the isolation of [Pt 2(μ-S2O2H)(PPh3) 4]+; crystallographic elucidation confirmed sulfide mono-oxygenation without S-S bonding to give formally [SO]2- in the form of an [SOHOS]3- overhead bridge. © 2009 The Royal Society of Chemistry.-
dc.languageeng-
dc.relation.ispartofChemical Communications-
dc.titleOne-pot oxidation and protonation of a bridging sulfide and rare crystallographic evidence of a coordinated [SO] complex in [Pt 2(μ-S2O2H)(PPh3) 4]+-
dc.typeArticle-
dc.description.naturelink_to_subscribed_fulltext-
dc.identifier.doi10.1039/b902625h-
dc.identifier.pmid19503889-
dc.identifier.scopuseid_2-s2.0-68049126042-
dc.identifier.issue23-
dc.identifier.spage3416-
dc.identifier.epage3418-
dc.identifier.isiWOS:000266674700028-
dc.identifier.issnl1359-7345-

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