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Article: Formation of [PtPd2(μ3-X)2(P-P)(dppmX) 2]2+ (X = S, Se; P-P = dppe, 2 × PPh3) aggregates through activation of the chalcogen-rich [PtX4] ring by a PdI-PdI bond

TitleFormation of [PtPd2(μ3-X)2(P-P)(dppmX) 2]2+ (X = S, Se; P-P = dppe, 2 × PPh3) aggregates through activation of the chalcogen-rich [PtX4] ring by a PdI-PdI bond
Authors
Issue Date2008
Citation
Dalton Transactions, 2008, n. 42, p. 5708-5711 How to Cite?
AbstractRedox addition of the Pd-Pd bond in [Pd2Cl2(dppm) 2] across S-S or Se-Se bond in [Pt(X4- κ2X1,X4)(P-P)] (X = S, Se; P-P = dppe or 2 × PPh3; dppm = bis(diphenylphosphino)methane, dppe = bis(diphenylphosphino)ethane) leads to the isolation of [PtPd 2(μ3-X)2(P-P)(dppmX-κ2X, P4)2]2+ and represents an atom-economy process that converts chalcogen-rich complexes to heterometallic chalcogenide aggregates. Activation of the [PtX4] ring is achieved by tetrachalcogenide reduction and dual oxidation of palladium and phosphine. © 2008 The Royal Society of Chemistry.
Persistent Identifierhttp://hdl.handle.net/10722/219593
ISSN
2015 Impact Factor: 4.177
2015 SCImago Journal Rankings: 1.404

 

DC FieldValueLanguage
dc.contributor.authorLi, Jingqiu-
dc.contributor.authorHor, T. S Andy-
dc.date.accessioned2015-09-23T02:57:28Z-
dc.date.available2015-09-23T02:57:28Z-
dc.date.issued2008-
dc.identifier.citationDalton Transactions, 2008, n. 42, p. 5708-5711-
dc.identifier.issn1477-9226-
dc.identifier.urihttp://hdl.handle.net/10722/219593-
dc.description.abstractRedox addition of the Pd-Pd bond in [Pd2Cl2(dppm) 2] across S-S or Se-Se bond in [Pt(X4- κ2X1,X4)(P-P)] (X = S, Se; P-P = dppe or 2 × PPh3; dppm = bis(diphenylphosphino)methane, dppe = bis(diphenylphosphino)ethane) leads to the isolation of [PtPd 2(μ3-X)2(P-P)(dppmX-κ2X, P4)2]2+ and represents an atom-economy process that converts chalcogen-rich complexes to heterometallic chalcogenide aggregates. Activation of the [PtX4] ring is achieved by tetrachalcogenide reduction and dual oxidation of palladium and phosphine. © 2008 The Royal Society of Chemistry.-
dc.languageeng-
dc.relation.ispartofDalton Transactions-
dc.titleFormation of [PtPd2(μ3-X)2(P-P)(dppmX) 2]2+ (X = S, Se; P-P = dppe, 2 × PPh3) aggregates through activation of the chalcogen-rich [PtX4] ring by a PdI-PdI bond-
dc.typeArticle-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.doi10.1039/b811493e-
dc.identifier.scopuseid_2-s2.0-54349111698-
dc.identifier.issue42-
dc.identifier.spage5708-
dc.identifier.epage5711-
dc.identifier.eissn1477-9234-

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