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Article: Isolation of an [SNS]Pd(II) pincer with a water ladder and its Suzuki coupling activity in water

TitleIsolation of an [SNS]Pd(II) pincer with a water ladder and its Suzuki coupling activity in water
Authors
Issue Date2008
Citation
Chemical Communications, 2008, n. 27, p. 3172-3174 How to Cite?
AbstractA water-compatible Pd(II) pincer with a hybrid [SNS]-donor set, [L 1PdCl]Cl·2H2O [L1 = bis-(2-(i- butylsulfanyl)-ethyl)-amine] has been isolated and crystallographically characterized; its solid lattice at 223 K contains a ladder-like water polymer of tetramers and extensive H-bonding exists among the cation, anion and water cluster, and this water-soluble complex is active in Suzuki-Miyaura coupling of phenylboronic acid and selected aryl bromides in water at 75°C. © The Royal Society of Chemistry.
Persistent Identifierhttp://hdl.handle.net/10722/219575
ISSN
2015 Impact Factor: 6.567
2015 SCImago Journal Rankings: 2.771

 

DC FieldValueLanguage
dc.contributor.authorBai, Shi Qiang-
dc.contributor.authorHor, T. S Andy-
dc.date.accessioned2015-09-23T02:57:26Z-
dc.date.available2015-09-23T02:57:26Z-
dc.date.issued2008-
dc.identifier.citationChemical Communications, 2008, n. 27, p. 3172-3174-
dc.identifier.issn1359-7345-
dc.identifier.urihttp://hdl.handle.net/10722/219575-
dc.description.abstractA water-compatible Pd(II) pincer with a hybrid [SNS]-donor set, [L 1PdCl]Cl·2H2O [L1 = bis-(2-(i- butylsulfanyl)-ethyl)-amine] has been isolated and crystallographically characterized; its solid lattice at 223 K contains a ladder-like water polymer of tetramers and extensive H-bonding exists among the cation, anion and water cluster, and this water-soluble complex is active in Suzuki-Miyaura coupling of phenylboronic acid and selected aryl bromides in water at 75°C. © The Royal Society of Chemistry.-
dc.languageeng-
dc.relation.ispartofChemical Communications-
dc.titleIsolation of an [SNS]Pd(II) pincer with a water ladder and its Suzuki coupling activity in water-
dc.typeArticle-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.doi10.1039/b802043d-
dc.identifier.scopuseid_2-s2.0-46249119363-
dc.identifier.issue27-
dc.identifier.spage3172-
dc.identifier.epage3174-

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