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Article: Facile ligand transformation from bridging thio to terminal chloromethanethiolato. Bridge opening of [Pt(μ-S)(dppf)]2 by dichloromethane to give Pt(SCH2Cl)2(dppf) [dppf Fe(C5H4PPh2)2]

TitleFacile ligand transformation from bridging thio to terminal chloromethanethiolato. Bridge opening of [Pt(μ-S)(dppf)]2 by dichloromethane to give Pt(SCH2Cl)2(dppf) [dppf Fe(C5H4PPh2)2]
Authors
KeywordsPlatinum
Sulfide
Diphosphine
Phosphine
Ferrocene
Thiolate
Issue Date1994
Citation
Journal of Organometallic Chemistry, 1994, v. 476, n. 2, p. c32-c34 How to Cite?
AbstractReaction of PtCl2(dppf) or [Pt(CH3CN)2(dppf)][BF4]2 with Na2S gives [Pt(μ-S)(dppf)]2. This bridging thio complex rapidly undergoes nucleophilic attack on CH2Cl2 to give [Pt2(μ-S)(μ-SCH2Cl)(dppf)2]Cl, which cleanly converts into [Pt(SCH2Cl)2(dppf)] with liberation of [PtCl2(dppf)]. These reactions effectively complete a cycle which yields a chloromethanethiolato complex from Na2S and CH2Cl2 via a thio complex. © 1994.
Persistent Identifierhttp://hdl.handle.net/10722/219573
ISSN
2015 Impact Factor: 2.336
2015 SCImago Journal Rankings: 0.732

 

DC FieldValueLanguage
dc.contributor.authorMeisheng, Zhou-
dc.contributor.authorChoon, Fui Lam-
dc.contributor.authorMok, K. F.-
dc.contributor.authorPak-Hing, Leung-
dc.contributor.authorHor, T. S Andy-
dc.date.accessioned2015-09-23T02:57:26Z-
dc.date.available2015-09-23T02:57:26Z-
dc.date.issued1994-
dc.identifier.citationJournal of Organometallic Chemistry, 1994, v. 476, n. 2, p. c32-c34-
dc.identifier.issn0022-328X-
dc.identifier.urihttp://hdl.handle.net/10722/219573-
dc.description.abstractReaction of PtCl2(dppf) or [Pt(CH3CN)2(dppf)][BF4]2 with Na2S gives [Pt(μ-S)(dppf)]2. This bridging thio complex rapidly undergoes nucleophilic attack on CH2Cl2 to give [Pt2(μ-S)(μ-SCH2Cl)(dppf)2]Cl, which cleanly converts into [Pt(SCH2Cl)2(dppf)] with liberation of [PtCl2(dppf)]. These reactions effectively complete a cycle which yields a chloromethanethiolato complex from Na2S and CH2Cl2 via a thio complex. © 1994.-
dc.languageeng-
dc.relation.ispartofJournal of Organometallic Chemistry-
dc.subjectPlatinum-
dc.subjectSulfide-
dc.subjectDiphosphine-
dc.subjectPhosphine-
dc.subjectFerrocene-
dc.subjectThiolate-
dc.titleFacile ligand transformation from bridging thio to terminal chloromethanethiolato. Bridge opening of [Pt(μ-S)(dppf)]2 by dichloromethane to give Pt(SCH2Cl)2(dppf) [dppf Fe(C5H4PPh2)2]-
dc.typeArticle-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.doi10.1016/0022-328X(94)87092-6-
dc.identifier.scopuseid_2-s2.0-43949159966-
dc.identifier.volume476-
dc.identifier.issue2-
dc.identifier.spagec32-
dc.identifier.epagec34-

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