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Article: Isolation and crystallographic characterization of solvate- and anion-stabilized PCP pincer complexes of palladium(II)

TitleIsolation and crystallographic characterization of solvate- and anion-stabilized PCP pincer complexes of palladium(II)
Authors
KeywordsPhosphine
Suzuki-Miyaura Coupling
Palladium
Pincer
Issue Date2008
Citation
Journal of Organometallic Chemistry, 2008, v. 693, n. 8-9, p. 1628-1635 How to Cite?
AbstractPincer PCP-Pd(II) complex [PdCl(PCP)] (1) (PCP = -CH(CH2CH2PPh2)2) reacts with AgNO3 to give [Pd(NO3)(PCP)] (2). Similar reaction with AgBF4 gives the aqua complex [Pd(OH2)(PCP)][BF4] (3) and the dinuclear complex [{Pd(PCP)}2(μ-Cl)][BF4] (4) with singly bridging chloro ligand. All new complexes were characterized by NMR spectroscopy, ESI-MS and single-crystal X-ray diffraction. Complex 1 and the triflate complex [Pd(OTf)(PCP)] (5) are active towards Suzuki-Miyaura coupling between aryl bromides and phenyl boronic acid. © 2007 Elsevier B.V. All rights reserved.
Persistent Identifierhttp://hdl.handle.net/10722/219565
ISSN
2015 Impact Factor: 2.336
2015 SCImago Journal Rankings: 0.732

 

DC FieldValueLanguage
dc.contributor.authorNeo, Kian Eang-
dc.contributor.authorHuynh, Han Vinh-
dc.contributor.authorKoh, Lip Lin-
dc.contributor.authorHenderson, William-
dc.contributor.authorHor, T. S Andy-
dc.date.accessioned2015-09-23T02:57:24Z-
dc.date.available2015-09-23T02:57:24Z-
dc.date.issued2008-
dc.identifier.citationJournal of Organometallic Chemistry, 2008, v. 693, n. 8-9, p. 1628-1635-
dc.identifier.issn0022-328X-
dc.identifier.urihttp://hdl.handle.net/10722/219565-
dc.description.abstractPincer PCP-Pd(II) complex [PdCl(PCP)] (1) (PCP = -CH(CH2CH2PPh2)2) reacts with AgNO3 to give [Pd(NO3)(PCP)] (2). Similar reaction with AgBF4 gives the aqua complex [Pd(OH2)(PCP)][BF4] (3) and the dinuclear complex [{Pd(PCP)}2(μ-Cl)][BF4] (4) with singly bridging chloro ligand. All new complexes were characterized by NMR spectroscopy, ESI-MS and single-crystal X-ray diffraction. Complex 1 and the triflate complex [Pd(OTf)(PCP)] (5) are active towards Suzuki-Miyaura coupling between aryl bromides and phenyl boronic acid. © 2007 Elsevier B.V. All rights reserved.-
dc.languageeng-
dc.relation.ispartofJournal of Organometallic Chemistry-
dc.subjectPhosphine-
dc.subjectSuzuki-Miyaura Coupling-
dc.subjectPalladium-
dc.subjectPincer-
dc.titleIsolation and crystallographic characterization of solvate- and anion-stabilized PCP pincer complexes of palladium(II)-
dc.typeArticle-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.doi10.1016/j.jorganchem.2007.11.031-
dc.identifier.scopuseid_2-s2.0-41549117150-
dc.identifier.volume693-
dc.identifier.issue8-9-
dc.identifier.spage1628-
dc.identifier.epage1635-

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