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Article: Pressure-assisted hetero- and homodialkylation of sulfide in [Pt 2(μ-S)2(dppp)2]: One-pot conversion of {Pt2(μ-S)2} into Pt2(SR)2J and {Pt2(SR)(SR′)}

TitlePressure-assisted hetero- and homodialkylation of sulfide in [Pt 2(μ-S)2(dppp)2]: One-pot conversion of {Pt2(μ-S)2} into Pt2(SR)2J and {Pt2(SR)(SR′)}
Authors
KeywordsAlkylation
Platinum
Sulfides
High-pressure chemistry
Dithiolate complexes
Issue Date2007
Citation
Chemistry - An Asian Journal, 2007, v. 2, n. 11, p. 1356-1362 How to Cite?
AbstractHeterodialkylation of [Pt2(μ-S)2] (dppp = Ph 2P(CH2)3PPh2) was achieved under high pressure (10 kbar). This enabled the synthesis of rare diplatinum complexes with structurally diverse thiolate bridges, such as [Pt2(μ-SC 5H10CO2CH2CH3)(μ- SC3H7)-(dppp)2](PF6)2, which was crystallographically identified. Complete homodialkylation was also achieved under similar conditions (6 kbar at room temperature), thus permitting the isolation of [Pt2(μ-SC2H4CO 2CH2CH3)2(dppp)2]- (PF6)2. The isolation of these complexes extends the applications of high-pressure chemistry to thiolato homo-and heterobridged complexes that are otherwise not accessible. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
Persistent Identifierhttp://hdl.handle.net/10722/219551
ISSN
2015 Impact Factor: 4.592
2015 SCImago Journal Rankings: 1.833

 

DC FieldValueLanguage
dc.contributor.authorChong, Siew Huay-
dc.contributor.authorYoung, David J.-
dc.contributor.authorHor, T. S Andy-
dc.date.accessioned2015-09-23T02:57:22Z-
dc.date.available2015-09-23T02:57:22Z-
dc.date.issued2007-
dc.identifier.citationChemistry - An Asian Journal, 2007, v. 2, n. 11, p. 1356-1362-
dc.identifier.issn1861-4728-
dc.identifier.urihttp://hdl.handle.net/10722/219551-
dc.description.abstractHeterodialkylation of [Pt2(μ-S)2] (dppp = Ph 2P(CH2)3PPh2) was achieved under high pressure (10 kbar). This enabled the synthesis of rare diplatinum complexes with structurally diverse thiolate bridges, such as [Pt2(μ-SC 5H10CO2CH2CH3)(μ- SC3H7)-(dppp)2](PF6)2, which was crystallographically identified. Complete homodialkylation was also achieved under similar conditions (6 kbar at room temperature), thus permitting the isolation of [Pt2(μ-SC2H4CO 2CH2CH3)2(dppp)2]- (PF6)2. The isolation of these complexes extends the applications of high-pressure chemistry to thiolato homo-and heterobridged complexes that are otherwise not accessible. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.-
dc.languageeng-
dc.relation.ispartofChemistry - An Asian Journal-
dc.subjectAlkylation-
dc.subjectPlatinum-
dc.subjectSulfides-
dc.subjectHigh-pressure chemistry-
dc.subjectDithiolate complexes-
dc.titlePressure-assisted hetero- and homodialkylation of sulfide in [Pt 2(μ-S)2(dppp)2]: One-pot conversion of {Pt2(μ-S)2} into Pt2(SR)2J and {Pt2(SR)(SR′)}-
dc.typeArticle-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.doi10.1002/asia.200700203-
dc.identifier.scopuseid_2-s2.0-35948998779-
dc.identifier.volume2-
dc.identifier.issue11-
dc.identifier.spage1356-
dc.identifier.epage1362-
dc.identifier.eissn1861-471X-

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