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Article: Metal unsaturation and ligand hemilability in Suzuki coupling

TitleMetal unsaturation and ligand hemilability in Suzuki coupling
Authors
Issue Date2007
Citation
Accounts of Chemical Research, 2007, v. 40, n. 8, p. 676-684 How to Cite?
AbstractThe combinative and complementary use of a hemilabile difunctional ligand on a metal, notably palladium, that is coordinatively and electronically unsaturated has led to the isolation of a string of unexpected low-valent complexes that are structurally intriguing. The ligands of interest are primarily ferrocenes functionalized by [P,N] and [P,O] donors. The characterization of these active Suzuki catalysts, which support sp 2-sp2 couplings, give valuable insights into the key Suzuki intermediates such as those arising from the reductive elimination, transmetallation, and oxidative addition steps. In this Account, we shall review and discuss our recent results in relation to selected developments in other laboratories. © 2007 American Chemical Society.
Persistent Identifierhttp://hdl.handle.net/10722/219546
ISSN
2015 Impact Factor: 22.003
2015 SCImago Journal Rankings: 11.465

 

DC FieldValueLanguage
dc.contributor.authorWeng, Zhiqiang-
dc.contributor.authorTeo, Shihui-
dc.contributor.authorHor, T. S Andy-
dc.date.accessioned2015-09-23T02:57:21Z-
dc.date.available2015-09-23T02:57:21Z-
dc.date.issued2007-
dc.identifier.citationAccounts of Chemical Research, 2007, v. 40, n. 8, p. 676-684-
dc.identifier.issn0001-4842-
dc.identifier.urihttp://hdl.handle.net/10722/219546-
dc.description.abstractThe combinative and complementary use of a hemilabile difunctional ligand on a metal, notably palladium, that is coordinatively and electronically unsaturated has led to the isolation of a string of unexpected low-valent complexes that are structurally intriguing. The ligands of interest are primarily ferrocenes functionalized by [P,N] and [P,O] donors. The characterization of these active Suzuki catalysts, which support sp 2-sp2 couplings, give valuable insights into the key Suzuki intermediates such as those arising from the reductive elimination, transmetallation, and oxidative addition steps. In this Account, we shall review and discuss our recent results in relation to selected developments in other laboratories. © 2007 American Chemical Society.-
dc.languageeng-
dc.relation.ispartofAccounts of Chemical Research-
dc.titleMetal unsaturation and ligand hemilability in Suzuki coupling-
dc.typeArticle-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.doi10.1021/ar600003h-
dc.identifier.scopuseid_2-s2.0-34548827700-
dc.identifier.volume40-
dc.identifier.issue8-
dc.identifier.spage676-
dc.identifier.epage684-

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