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Article: Substituted metal carbonyls-XIV. Polynuclear heterometallic complexes of Cr, Mo, W and Mn supported by singly-bridging 1,1′-bis(diphenylphosphino)ferrocene

TitleSubstituted metal carbonyls-XIV. Polynuclear heterometallic complexes of Cr, Mo, W and Mn supported by singly-bridging 1,1′-bis(diphenylphosphino)ferrocene
Authors
Issue Date1990
Citation
Polyhedron, 1990, v. 9, n. 18, p. 2305-2308 How to Cite?
AbstractA series of polynuclear heterometallic complexes (OC)5M(μ-dppf)M′(CO)5 (M, M′ = Cr, Mo, W; M ≠ M′) and (OC)5M(μ-dppf)Mn2(CO)9 (dppf = 1,1′-bis(diphenylphosphino) ferrocene) has been synthesized at room temperature based on the metallo-ligand M(CO)5(η1-dppf). The use of amine oxide as a decarbonylant preserves the integrity of the MnMn bond. The mixed metals are linked by a singly-bridging diphosphine group which does not perturb the two metal spheres. © 1990.
Persistent Identifierhttp://hdl.handle.net/10722/219520
ISSN
2015 Impact Factor: 2.108
2015 SCImago Journal Rankings: 0.592

 

DC FieldValueLanguage
dc.contributor.authorHor, T. S A-
dc.contributor.authorPhang, L. T.-
dc.date.accessioned2015-09-23T02:57:17Z-
dc.date.available2015-09-23T02:57:17Z-
dc.date.issued1990-
dc.identifier.citationPolyhedron, 1990, v. 9, n. 18, p. 2305-2308-
dc.identifier.issn0277-5387-
dc.identifier.urihttp://hdl.handle.net/10722/219520-
dc.description.abstractA series of polynuclear heterometallic complexes (OC)5M(μ-dppf)M′(CO)5 (M, M′ = Cr, Mo, W; M ≠ M′) and (OC)5M(μ-dppf)Mn2(CO)9 (dppf = 1,1′-bis(diphenylphosphino) ferrocene) has been synthesized at room temperature based on the metallo-ligand M(CO)5(η1-dppf). The use of amine oxide as a decarbonylant preserves the integrity of the MnMn bond. The mixed metals are linked by a singly-bridging diphosphine group which does not perturb the two metal spheres. © 1990.-
dc.languageeng-
dc.relation.ispartofPolyhedron-
dc.titleSubstituted metal carbonyls-XIV. Polynuclear heterometallic complexes of Cr, Mo, W and Mn supported by singly-bridging 1,1′-bis(diphenylphosphino)ferrocene-
dc.typeArticle-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.doi10.1016/S0277-5387(00)86958-2-
dc.identifier.scopuseid_2-s2.0-33748716780-
dc.identifier.volume9-
dc.identifier.issue18-
dc.identifier.spage2305-
dc.identifier.epage2308-

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