File Download

There are no files associated with this item.

  Links for fulltext
     (May Require Subscription)
Supplementary

Article: Silver decoration of a palladacycle through "spacer-guest" interaction

TitleSilver decoration of a palladacycle through "spacer-guest" interaction
Authors
KeywordsPalladium
Silver
Spacer-guest
Heterometallic
Host-guest interaction
Macrocycle
Issue Date2006
Citation
Inorganica Chimica Acta, 2006, v. 359, n. 11, p. 3435-3439 How to Cite?
Abstract[Pd(dppf)(MeCN)2](OTf)2 [dppf = 1,1′-bis(diphenylphosphino)ferrocene, OTf = triflate] reacts with pyridyl acetic acid (PyAcOH) to yield a dipalladium ring structure, [Pd2(dppf)2(μ-PyOAc)2](OTf)2 (1). The doubly-bridging ligands exhibit basicity at the pendant carboxyl oxygen to attract AgX (X = OTf or CF3CO2) to form [Pd2Ag2(dppf)2(PyOAc)2(OTf)4] (2) and [Pd2Ag2(dppf)2(PyOAc)2(OTf)2(CF3CO2)2] (3), respectively. Complexes 1 and 2 have been crystallographically characterized. Similar spacer-guest affinity is not found in the Pt(II) or isonicotinate analogues. © 2005 Elsevier B.V. All rights reserved.
Persistent Identifierhttp://hdl.handle.net/10722/219510
ISSN
2015 Impact Factor: 1.918
2015 SCImago Journal Rankings: 0.584

 

DC FieldValueLanguage
dc.contributor.authorTeo, Peili-
dc.contributor.authorKoh, L. L.-
dc.contributor.authorHor, T. S Andy-
dc.date.accessioned2015-09-23T02:57:16Z-
dc.date.available2015-09-23T02:57:16Z-
dc.date.issued2006-
dc.identifier.citationInorganica Chimica Acta, 2006, v. 359, n. 11, p. 3435-3439-
dc.identifier.issn0020-1693-
dc.identifier.urihttp://hdl.handle.net/10722/219510-
dc.description.abstract[Pd(dppf)(MeCN)2](OTf)2 [dppf = 1,1′-bis(diphenylphosphino)ferrocene, OTf = triflate] reacts with pyridyl acetic acid (PyAcOH) to yield a dipalladium ring structure, [Pd2(dppf)2(μ-PyOAc)2](OTf)2 (1). The doubly-bridging ligands exhibit basicity at the pendant carboxyl oxygen to attract AgX (X = OTf or CF3CO2) to form [Pd2Ag2(dppf)2(PyOAc)2(OTf)4] (2) and [Pd2Ag2(dppf)2(PyOAc)2(OTf)2(CF3CO2)2] (3), respectively. Complexes 1 and 2 have been crystallographically characterized. Similar spacer-guest affinity is not found in the Pt(II) or isonicotinate analogues. © 2005 Elsevier B.V. All rights reserved.-
dc.languageeng-
dc.relation.ispartofInorganica Chimica Acta-
dc.subjectPalladium-
dc.subjectSilver-
dc.subjectSpacer-guest-
dc.subjectHeterometallic-
dc.subjectHost-guest interaction-
dc.subjectMacrocycle-
dc.titleSilver decoration of a palladacycle through "spacer-guest" interaction-
dc.typeArticle-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.doi10.1016/j.ica.2005.06.078-
dc.identifier.scopuseid_2-s2.0-33745712286-
dc.identifier.volume359-
dc.identifier.issue11-
dc.identifier.spage3435-
dc.identifier.epage3439-

Export via OAI-PMH Interface in XML Formats


OR


Export to Other Non-XML Formats