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Article: Crystal structures and characterizations of (nitrato-O) (nitrato-O,O′)(η6-hexamethylbenzene)ruthenium(II) and di(trifluoroacetato-O)(H2O-O)(η6-hexamethylbenzene) ruthenium(II)

TitleCrystal structures and characterizations of (nitrato-O) (nitrato-O,O′)(η6-hexamethylbenzene)ruthenium(II) and di(trifluoroacetato-O)(H2O-O)(η6-hexamethylbenzene) ruthenium(II)
Authors
KeywordsHexamethylbenzene
Nitrate
Ruthenium
Structure
Trifluoroacetate
Issue Date2005
Citation
Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry, 2005, v. 35, n. 10, p. 743-746 How to Cite?
AbstractThe title complexes [(HMB)Ru(NO3)2] (HMB = η6-C6Me6) (1) and [(HMB)Ru(O 2CCF3)2(H2O)] (2) were spectroscopically characterized and their structures were determined by single-crystal diffraction analysis. In both compounds, the Ru atom is η6-coordinated to a hexamethylbenzene ring and three oxygen donor atoms in a "three-legged piano stool" arrangement. In the asymmetric unit of 1, ruthenium atom is coordinated to two nitrato ligands, one of which is η1-O coordinated and the second bidentate via both oxygen atoms; while in the symmetric unit of 2, two disordered trifluoroacetate ligands are monodentate, symmetrically bound to the ruthenium atom, and the pseudo-octahedral geometry is completed by an oxygen atom from a H2O molecule, which is hydrogen-bonded to both acetate ligands. Copyright © 2005 Taylor & Francis, Inc.
Persistent Identifierhttp://hdl.handle.net/10722/219507
ISSN
2015 Impact Factor: 0.493
2015 SCImago Journal Rankings: 0.184

 

DC FieldValueLanguage
dc.contributor.authorLu, Xiu Lian-
dc.contributor.authorLeong, Weng Kee-
dc.contributor.authorGoh, Lai Yoong-
dc.contributor.authorHor, Tzi Sum Andy-
dc.contributor.authorVittal, Jagadese J.-
dc.date.accessioned2015-09-23T02:57:15Z-
dc.date.available2015-09-23T02:57:15Z-
dc.date.issued2005-
dc.identifier.citationSynthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry, 2005, v. 35, n. 10, p. 743-746-
dc.identifier.issn1553-3174-
dc.identifier.urihttp://hdl.handle.net/10722/219507-
dc.description.abstractThe title complexes [(HMB)Ru(NO3)2] (HMB = η6-C6Me6) (1) and [(HMB)Ru(O 2CCF3)2(H2O)] (2) were spectroscopically characterized and their structures were determined by single-crystal diffraction analysis. In both compounds, the Ru atom is η6-coordinated to a hexamethylbenzene ring and three oxygen donor atoms in a "three-legged piano stool" arrangement. In the asymmetric unit of 1, ruthenium atom is coordinated to two nitrato ligands, one of which is η1-O coordinated and the second bidentate via both oxygen atoms; while in the symmetric unit of 2, two disordered trifluoroacetate ligands are monodentate, symmetrically bound to the ruthenium atom, and the pseudo-octahedral geometry is completed by an oxygen atom from a H2O molecule, which is hydrogen-bonded to both acetate ligands. Copyright © 2005 Taylor & Francis, Inc.-
dc.languageeng-
dc.relation.ispartofSynthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry-
dc.subjectHexamethylbenzene-
dc.subjectNitrate-
dc.subjectRuthenium-
dc.subjectStructure-
dc.subjectTrifluoroacetate-
dc.titleCrystal structures and characterizations of (nitrato-O) (nitrato-O,O′)(η6-hexamethylbenzene)ruthenium(II) and di(trifluoroacetato-O)(H2O-O)(η6-hexamethylbenzene) ruthenium(II)-
dc.typeArticle-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.doi10.1080/15533170500360164-
dc.identifier.scopuseid_2-s2.0-33645534943-
dc.identifier.volume35-
dc.identifier.issue10-
dc.identifier.spage743-
dc.identifier.epage746-
dc.identifier.eissn1553-3182-

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