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Article: Ethylene oligomerization at coordinatively and electronically unsaturated low-valent nickel

TitleEthylene oligomerization at coordinatively and electronically unsaturated low-valent nickel
Authors
KeywordsNickel
Homogeneous catalysis
Coordination modes
Oligomerization
N,P ligands
Issue Date2005
Citation
Angewandte Chemie - International Edition, 2005, v. 44, n. 46, p. 7560-7564 How to Cite?
Abstract(Chemical Equation Presented) Three modes: An iminoferrocenylphosphane ligand stabilizes low-coordinate and low-valent nickel in [{[η-C 5H4CH=N-(C6H5)]Fe[η-C 5H4P(tBu)2]-N,P}NiICl] (see figure) and similar complexes. The coordination environment is hemilabile as exemplified by three different coordination modes: P,N(σ)-chelate, P,CN(π)-chelate, and P unidentate. These complexes are catalytically active towards ethylene oligomerization. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.
Persistent Identifierhttp://hdl.handle.net/10722/219499
ISSN
2015 Impact Factor: 11.709
2015 SCImago Journal Rankings: 6.229

 

DC FieldValueLanguage
dc.contributor.authorWeng, Zhiqiang-
dc.contributor.authorTeo, Shihui-
dc.contributor.authorLip, Lin Koh-
dc.contributor.authorHor, T. S Andy-
dc.date.accessioned2015-09-23T02:57:14Z-
dc.date.available2015-09-23T02:57:14Z-
dc.date.issued2005-
dc.identifier.citationAngewandte Chemie - International Edition, 2005, v. 44, n. 46, p. 7560-7564-
dc.identifier.issn1433-7851-
dc.identifier.urihttp://hdl.handle.net/10722/219499-
dc.description.abstract(Chemical Equation Presented) Three modes: An iminoferrocenylphosphane ligand stabilizes low-coordinate and low-valent nickel in [{[η-C 5H4CH=N-(C6H5)]Fe[η-C 5H4P(tBu)2]-N,P}NiICl] (see figure) and similar complexes. The coordination environment is hemilabile as exemplified by three different coordination modes: P,N(σ)-chelate, P,CN(π)-chelate, and P unidentate. These complexes are catalytically active towards ethylene oligomerization. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.-
dc.languageeng-
dc.relation.ispartofAngewandte Chemie - International Edition-
dc.subjectNickel-
dc.subjectHomogeneous catalysis-
dc.subjectCoordination modes-
dc.subjectOligomerization-
dc.subjectN,P ligands-
dc.titleEthylene oligomerization at coordinatively and electronically unsaturated low-valent nickel-
dc.typeArticle-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.doi10.1002/anie.200502532-
dc.identifier.scopuseid_2-s2.0-28244483134-
dc.identifier.volume44-
dc.identifier.issue46-
dc.identifier.spage7560-
dc.identifier.epage7564-

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