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Article: Suzuki cross-coupling in aqueous media catalyzed by a 1,1′-N-substituted ferrocenediyl Pd(II) complex

TitleSuzuki cross-coupling in aqueous media catalyzed by a 1,1′-N-substituted ferrocenediyl Pd(II) complex
Authors
KeywordsPalladium
Suzuki coupling
1,1′-Ferrocenediyl
Aqueous
Catalysis
Issue Date2004
Citation
Journal of Organometallic Chemistry, 2004, v. 689, n. 1, p. 18-24 How to Cite?
AbstractReaction of PdCl2(MeCN)2 with Fe[η-C5H4NC(H)Ph-N]2 (1) at MeOH at r.t. gives air-stable PdCl2Fe[η-C5 H4NC(H)Ph-N]2 (2; yield 84%). X-ray single-crystal diffraction analyses show that 2 is a Pd(II) square planar complex with N,N′ chelation of the ferrocenediyl ligand, without Fe-Pd bond. It effectively catalyzes Suzuki cross-coupling reactions of aryl iodides and bromides with aryl boronic acids in aqueous media under non-homogeneous conditions in which the products can be easily isolated. The reaction conditions including choice of base, catalytic load and catalyst recoverability have been investigated and reported. © 2003 Elsevier B.V. All rights reserved.
Persistent Identifierhttp://hdl.handle.net/10722/219479
ISSN
2015 Impact Factor: 2.336
2015 SCImago Journal Rankings: 0.732

 

DC FieldValueLanguage
dc.contributor.authorWeng, Zhiqiang-
dc.contributor.authorKoh, Lip Lin-
dc.contributor.authorHor, T. S Andy-
dc.date.accessioned2015-09-23T02:57:11Z-
dc.date.available2015-09-23T02:57:11Z-
dc.date.issued2004-
dc.identifier.citationJournal of Organometallic Chemistry, 2004, v. 689, n. 1, p. 18-24-
dc.identifier.issn0022-328X-
dc.identifier.urihttp://hdl.handle.net/10722/219479-
dc.description.abstractReaction of PdCl2(MeCN)2 with Fe[η-C5H4NC(H)Ph-N]2 (1) at MeOH at r.t. gives air-stable PdCl2Fe[η-C5 H4NC(H)Ph-N]2 (2; yield 84%). X-ray single-crystal diffraction analyses show that 2 is a Pd(II) square planar complex with N,N′ chelation of the ferrocenediyl ligand, without Fe-Pd bond. It effectively catalyzes Suzuki cross-coupling reactions of aryl iodides and bromides with aryl boronic acids in aqueous media under non-homogeneous conditions in which the products can be easily isolated. The reaction conditions including choice of base, catalytic load and catalyst recoverability have been investigated and reported. © 2003 Elsevier B.V. All rights reserved.-
dc.languageeng-
dc.relation.ispartofJournal of Organometallic Chemistry-
dc.subjectPalladium-
dc.subjectSuzuki coupling-
dc.subject1,1′-Ferrocenediyl-
dc.subjectAqueous-
dc.subjectCatalysis-
dc.titleSuzuki cross-coupling in aqueous media catalyzed by a 1,1′-N-substituted ferrocenediyl Pd(II) complex-
dc.typeArticle-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.doi10.1016/j.jorganchem.2003.09.028-
dc.identifier.scopuseid_2-s2.0-0348220962-
dc.identifier.volume689-
dc.identifier.issue1-
dc.identifier.spage18-
dc.identifier.epage24-

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