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- Publisher Website: 10.1016/j.jorganchem.2003.09.028
- Scopus: eid_2-s2.0-0348220962
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Article: Suzuki cross-coupling in aqueous media catalyzed by a 1,1′-N-substituted ferrocenediyl Pd(II) complex
Title | Suzuki cross-coupling in aqueous media catalyzed by a 1,1′-N-substituted ferrocenediyl Pd(II) complex |
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Authors | |
Keywords | Palladium Suzuki coupling 1,1′-Ferrocenediyl Aqueous Catalysis |
Issue Date | 2004 |
Citation | Journal of Organometallic Chemistry, 2004, v. 689, n. 1, p. 18-24 How to Cite? |
Abstract | Reaction of PdCl2(MeCN)2 with Fe[η-C5H4NC(H)Ph-N]2 (1) at MeOH at r.t. gives air-stable PdCl2Fe[η-C5 H4NC(H)Ph-N]2 (2; yield 84%). X-ray single-crystal diffraction analyses show that 2 is a Pd(II) square planar complex with N,N′ chelation of the ferrocenediyl ligand, without Fe-Pd bond. It effectively catalyzes Suzuki cross-coupling reactions of aryl iodides and bromides with aryl boronic acids in aqueous media under non-homogeneous conditions in which the products can be easily isolated. The reaction conditions including choice of base, catalytic load and catalyst recoverability have been investigated and reported. © 2003 Elsevier B.V. All rights reserved. |
Persistent Identifier | http://hdl.handle.net/10722/219479 |
ISSN | 2023 Impact Factor: 2.1 2023 SCImago Journal Rankings: 0.359 |
ISI Accession Number ID |
DC Field | Value | Language |
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dc.contributor.author | Weng, Zhiqiang | - |
dc.contributor.author | Koh, Lip Lin | - |
dc.contributor.author | Hor, T. S Andy | - |
dc.date.accessioned | 2015-09-23T02:57:11Z | - |
dc.date.available | 2015-09-23T02:57:11Z | - |
dc.date.issued | 2004 | - |
dc.identifier.citation | Journal of Organometallic Chemistry, 2004, v. 689, n. 1, p. 18-24 | - |
dc.identifier.issn | 0022-328X | - |
dc.identifier.uri | http://hdl.handle.net/10722/219479 | - |
dc.description.abstract | Reaction of PdCl2(MeCN)2 with Fe[η-C5H4NC(H)Ph-N]2 (1) at MeOH at r.t. gives air-stable PdCl2Fe[η-C5 H4NC(H)Ph-N]2 (2; yield 84%). X-ray single-crystal diffraction analyses show that 2 is a Pd(II) square planar complex with N,N′ chelation of the ferrocenediyl ligand, without Fe-Pd bond. It effectively catalyzes Suzuki cross-coupling reactions of aryl iodides and bromides with aryl boronic acids in aqueous media under non-homogeneous conditions in which the products can be easily isolated. The reaction conditions including choice of base, catalytic load and catalyst recoverability have been investigated and reported. © 2003 Elsevier B.V. All rights reserved. | - |
dc.language | eng | - |
dc.relation.ispartof | Journal of Organometallic Chemistry | - |
dc.subject | Palladium | - |
dc.subject | Suzuki coupling | - |
dc.subject | 1,1′-Ferrocenediyl | - |
dc.subject | Aqueous | - |
dc.subject | Catalysis | - |
dc.title | Suzuki cross-coupling in aqueous media catalyzed by a 1,1′-N-substituted ferrocenediyl Pd(II) complex | - |
dc.type | Article | - |
dc.description.nature | link_to_subscribed_fulltext | - |
dc.identifier.doi | 10.1016/j.jorganchem.2003.09.028 | - |
dc.identifier.scopus | eid_2-s2.0-0348220962 | - |
dc.identifier.volume | 689 | - |
dc.identifier.issue | 1 | - |
dc.identifier.spage | 18 | - |
dc.identifier.epage | 24 | - |
dc.identifier.isi | WOS:000188066400004 | - |
dc.identifier.issnl | 0022-328X | - |