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Article: Unusual Coordination Assemblies from Platinum(II) Thienyl and Bithienyl Complexes

TitleUnusual Coordination Assemblies from Platinum(II) Thienyl and Bithienyl Complexes
Authors
Issue Date2003
Citation
Inorganic Chemistry, 2003, v. 42, n. 22, p. 7290-7296 How to Cite?
AbstractDinuclear Pt2Br2(dppf)2(μ-C BH4S2) exchanges with isonicotinic acid to release free bithiophene and gives a molecular square [Pt4(dppf) 4(μ2-O2CC5H4N) 4]4+4OTf- which is an "all-ring" system with four Pt rings disposed at the corners of a larger macrocyclic ring. The related mononuclear complex PtBr(η1(C2)-C4H 3S)(dppf) reacts with AgOTf (OTf = triflate) to give [Pt 2(dppf)2(μ2,η1(C),η 1(S)-C4H3S)2]2+2OTf - with an unusual six-membered ring formed by the fusion of two Pt-thienyl entities at the sulfur sites. All the complexes are structurally characterized by single-crystal X-ray crystallography.
Persistent Identifierhttp://hdl.handle.net/10722/219472
ISSN
2015 Impact Factor: 4.82
2015 SCImago Journal Rankings: 1.873

 

DC FieldValueLanguage
dc.contributor.authorTeo, Peili-
dc.contributor.authorKoh, L. L.-
dc.contributor.authorHor, T. S Andy-
dc.date.accessioned2015-09-23T02:57:10Z-
dc.date.available2015-09-23T02:57:10Z-
dc.date.issued2003-
dc.identifier.citationInorganic Chemistry, 2003, v. 42, n. 22, p. 7290-7296-
dc.identifier.issn0020-1669-
dc.identifier.urihttp://hdl.handle.net/10722/219472-
dc.description.abstractDinuclear Pt2Br2(dppf)2(μ-C BH4S2) exchanges with isonicotinic acid to release free bithiophene and gives a molecular square [Pt4(dppf) 4(μ2-O2CC5H4N) 4]4+4OTf- which is an "all-ring" system with four Pt rings disposed at the corners of a larger macrocyclic ring. The related mononuclear complex PtBr(η1(C2)-C4H 3S)(dppf) reacts with AgOTf (OTf = triflate) to give [Pt 2(dppf)2(μ2,η1(C),η 1(S)-C4H3S)2]2+2OTf - with an unusual six-membered ring formed by the fusion of two Pt-thienyl entities at the sulfur sites. All the complexes are structurally characterized by single-crystal X-ray crystallography.-
dc.languageeng-
dc.relation.ispartofInorganic Chemistry-
dc.titleUnusual Coordination Assemblies from Platinum(II) Thienyl and Bithienyl Complexes-
dc.typeArticle-
dc.description.natureLink_to_subscribed_fulltext-
dc.identifier.doi10.1021/ic034690u-
dc.identifier.scopuseid_2-s2.0-0242290386-
dc.identifier.volume42-
dc.identifier.issue22-
dc.identifier.spage7290-
dc.identifier.epage7296-

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